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Title: Metal‐Mediated Directional Capping of Rod‐Packing Metal–Organic Frameworks
Award ID(s):
1663360
PAR ID:
10422413
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ;
Date Published:
Journal Name:
Chemistry – A European Journal
Volume:
28
Issue:
52
ISSN:
0947-6539
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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    Abstract Metal–organic frameworks (MOFs) are crystalline, 2‐ and 3‐dimensional coordination polymers formed by bonding interactions between metals and multitopic organic ligands. These are typically formed using hard Lewis basic organic ligands with high oxidation state metal ions. The use of low‐valent metals as structural elements in MOFs is far less common, despite the widespread use of such metals for catalysis, luminescence, and other applications. This Minireview focuses on recent advances in the field of low‐valent MOFs and offers a perspective on the future development of these materials. 
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