skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Tandem Use of Multiple Tracers and Metrics to Identify Dynamic and Slow Hydrological Flowpaths
Current understanding of the dynamic and slow flow paths that support streamflow in mountain headwater catchments is inhibited by the lack of long-term hydrogeochemical data and the frequent use of short residence time age tracers. To address this, the current study combined the traditional mean transit time and the state-of-the-art fraction of young water ( F yw ) metrics with stable water isotopes and tritium tracers to characterize the dynamic and slow flow paths at Marshall Gulch, a sub-humid headwater catchment in the Santa Catalina Mountains, Arizona, USA. The results show that F yw varied significantly with period when using sinusoidal curve fitting methods (e.g., iteratively re-weighted least squares or IRLS), but not when using the transit time distribution (TTD)-based method. Therefore, F yw estimates from TTD-based methods may be particularly useful for intercomparison of dynamic flow behavior between catchments. However, the utility of 3 H to determine F yw in deeper groundwater was limited due to both data quality and inconsistent seasonal cyclicity of the precipitation 3 H time series data. Although a Gamma-type TTD was appropriate to characterize deep groundwater, there were large uncertainties in the estimated Gamma TTD shape parameter arising from the short record length of 3 H in deep groundwater. This work demonstrates how co-application of multiple metrics and tracers can yield a more complete understanding of the dynamic and slow flow paths and observable deep groundwater storage volumes that contribute to streamflow in mountain headwater catchments.  more » « less
Award ID(s):
2012123
PAR ID:
10423536
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ;
Date Published:
Journal Name:
Frontiers in Water
Volume:
4
ISSN:
2624-9375
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract Mountain System Recharge processes are significant natural recharge pathways in many arid and semi‐arid mountainous regions. However, Mountain System Recharge processes are often poorly understood and characterized in hydrologic models. Mountains are the primary water supply source to valley aquifers via lateral groundwater flow from the mountain block (Mountain Block Recharge) and focused recharge from mountain streams contributing to focused Mountain Front Recharge at the piedmont zone. Here, we present a multi‐tool isogeochemical approach to characterize mountain flow paths and Mountain System Recharge in the northern Tulare Basin, California. We used groundwater chemistry data to delineate hydrochemical facies and explain the chemical evolution of groundwater from the Sierra Nevada to the Central Valley aquifer. Stable isotopes and radiogenic groundwater tracers validated Mountain System Recharge processes by differentiating focused from diffuse recharge, and estimating apparent groundwater age, respectively. Novel application of End‐Member Mixing Analysis using conservative chemical components revealed three Mountain System Recharge end‐members: (a) evaporated Ca‐HCO3water type associated with focused Mountain Front Recharge, (b) non‐evaporated Ca‐HCO3and Na‐HCO3water types with short residence times associated with shallow Mountain Block Recharge, and (c) Na‐HCO3groundwater type with long residence time associated with deep Mountain Block Recharge. We quantified the contribution of each Mountain System Recharge process to the valley aquifer by calculating mixing ratios. Our results show that deep Mountain Block Recharge is a significant recharge component, representing 31%–53% of the valley groundwater. Greater hydraulic connectivity between the Sierra Nevada and Central Valley has significant implications for parameterizing groundwater flow models. Our framework is useful for understanding Mountain System Recharge processes in other snow‐dominated mountain watersheds. 
    more » « less
  2. ABSTRACT The importance of subsurface water dynamics, such as water storage and flow partitioning, is well recognised. Yet, our understanding of their drivers and links to streamflow generation has remained elusive, especially in small headwater streams that are often data‐limited but crucial for downstream water quantity and quality. Large‐scale analyses have focused on streamflow characteristics across rivers with varying drainage areas, often overlooking the subsurface water dynamics that shape streamflow behaviour. Here we ask the question:What are the climate and landscape characteristics that regulate subsurface dynamic storage, flow path partitioning, and dynamics of streamflow generation in headwater streams?To answer this question, we used streamflow data and a widely‐used hydrological model (HBV) for 15 headwater catchments across the contiguous United States. Results show that climate characteristics such as aridity and precipitation phase (snow or rain) and land attributes such as topography and soil texture are key drivers of streamflow generation dynamics. In particular, steeper slopes generally promoted more streamflow, regardless of aridity. Streams in flat, rainy sites (< 30% precipitation as snow) with finer soils exhibited flashier regimes than those in snowy sites (> 30% precipitation as snow) or sites with coarse soils and deeper flow paths. In snowy sites, less weathered, thinner soils promoted shallower flow paths such that discharge was more sensitive to changes in storage, but snow dampened streamflow flashiness overall. Results here indicate that land characteristics such as steepness and soil texture modify subsurface water storage and shallow and deep flow partitioning, ultimately regulating streamflow response to climate forcing. As climate change increases uncertainty in water availability, understanding the interacting climate and landscape features that regulate streamflow will be essential to predict hydrological shifts in headwater catchments and improve water resources management. 
    more » « less
  3. Abstract The timescales associated with precipitation moving through watersheds reveal processes that are critical to understanding many hydrologic systems. Measurements of environmental stable water isotope ratios (δ2H and δ18O) have been used as tracers to study hydrologic timescales by examining how long it takes for incoming precipitation tracers become stream discharge, yet limited measurements both spatially and temporally have bounded macroscale evaluations so far. In this observation driven study across North American biomes within the National Ecological Observation Network (NEON), we examined δ18O and δ2H stable water isotope in precipitation (δP) and stream water (δQ) at 26 co‐located sites. With an average 54 precipitation samples and 139 stream water samples per site collected over 2014–2022, assessment of local meteoric water lines and local stream water lines showed geographic variation across North America. Taking the ratio of estimated seasonal amplitudes of δP and δQ to calculate young water fractions (Fyw), showed aFywrange from 1% to 93% with most sites havingFywbelow 20%. Calculated mean transit times (MTT) based on a gamma convolution model showed a MTT range from 0.10 to 13.2 years, with half of the sites having MTT estimates lower than 2 years. Significant correlations were found between theFywand watershed area, longest flow length, and the longest flow length/slope. Significant correlations were found between MTT and site latitude, longitude, slope, clay fraction, temperature, precipitation magnitude, and precipitation frequency. The significant correlations between water timescale metrics and the environmental characteristics we report share some similarities with those reported in prior studies, demonstrating that these quantities are primarily driven by site or area specific factors. The analysis of isotope data presented here provides important constraints on isotope variation in North American biomes and the timescales of water movement through NEON study sites. 
    more » « less
  4. Intermittent headwater streams are highly vulnerable to environmental disturbances, but effective management of these water resources requires first understanding the mechanisms that generate streamflow. This study examined mechanisms governing streamflow generation in merokarst terrains, a type of carbonate terrain that covers much of the central United States yet has received relatively little attention in hydrological studies. We used high-frequency sampling of precipitation, stream water, and groundwater during summer 2021 to quantify the contributions to streamflow from different water sources and characterize their short-term dynamics in a 1.2 km 2 merokarst catchment at the Konza Prairie Biological Station (Kansas, USA). Mixing calculations using stable water isotopes and dissolved ions indicate that streamflow is overwhelmingly contributed by groundwater discharge from thin (1–2 m) limestone aquifers, even during wet periods, when soil water and surface runoff are generally expected to be more important. Relationships between hydraulic heads in the aquifers and their contributions to streamflow differed early in the study period compared to later, after a major storm occurred, suggesting there is a critical threshold of groundwater storage that the bedrock needs to attain before fully connecting to the stream. Furthermore, contributions from each limestone unit varied during the study period in response to differences in their hydrogeological properties and/or their stratigraphic position, which in turn impacted both the length of streamflow and its composition. Taken together, we interpret that the subsurface storage threshold and variation in aquifer properties are major controllers of flow intermittency in merokarst headwater catchments. 
    more » « less
  5. Abstract Headwater catchments have strong impacts on downstream waterways, near‐shore ecosystems, and the quality of water available for growing human populations. Thus, understanding how water and solutes are exported through these upland landscapes is critically important. A growing body of literature highlights the interaction of topography, climate, and the critical zone structure as a key control on streamflow and chemical export. However, more focused work is needed to pinpoint how variability in subsurface structure across lithologically complex regions impacts streamflow and chemical signals at catchment outlets. Here, we aim to better understand how lithology and subsurface critical zones modulate streamflow response and solute export patterns in two central coastal California headwater catchments that are similar in topography, vegetation, and climate but have different lithologies. We monitored streamflow and collected surface water samples at the catchment outlets for dissolved major ions and organic carbon (DOC) for two consecutive water years. The catchment with mélange bedrock displayed much flashier hydrologic behavior with 7.8 times higher peak flow values and 1.9 times higher mean event concentrations of DOC, suggesting shorter and shallower hydrologic flow paths that likely arise from regions of shallower bedrock. Despite distinct hydrologic behavior and DOC export, dissolved major ion concentrations were broadly similar and chemostatic, which may be driven by rapid chemical reactions in the critical zone of both catchments. Our work contributes to building an integrated understanding of how subtle differences in catchment structure can have profound impacts on how water and solutes are routed through headwater catchments. 
    more » « less