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The domain structure of a fluid ferroelectric nematic is dramatically different from the domain structure of solid ferroelectrics since it is not restricted by rectilinear crystallographic axes and planar surface facets. We demonstrate that thin films of a ferroelectric nematic seeded by colloidal inclusions produce domain walls (DWs) in the shape of conics such as a parabola. These conics reduce the bound charge within the domains and at the DWs. An adequate description of the domain structures requires one to analyze the electrostatic energy, which is a challenging task. Instead, we demonstrate that a good approximation to the experimentally observed polydomain textures is obtained when the divergence of spontaneous polarization—which causes the bound charge—is heavily penalized by assuming that the elastic constant of splay in the Oseen-Frank energy is much larger than those for twist and bend. The model takes advantage of the fact that the polarization vector is essentially parallel to the nematic director throughout the sample. Published by the American Physical Society2024
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Ferroelectric nematic liquids with conics
Abstract Spontaneous electric polarization of solid ferroelectrics follows aligning directions of crystallographic axes. Domains of differently oriented polarization are separated by domain walls (DWs), which are predominantly flat and run along directions dictated by the bulk translational order and the sample surfaces. Here we explore DWs in a ferroelectric nematic (N F ) liquid crystal, which is a fluid with polar long-range orientational order but no crystallographic axes nor facets. We demonstrate that DWs in the absence of bulk and surface aligning axes are shaped as conic sections. The conics bisect the angle between two neighboring polarization fields to avoid electric charges. The remarkable bisecting properties of conic sections, known for millennia, play a central role as intrinsic features of liquid ferroelectrics. The findings could be helpful in designing patterns of electric polarization and space charge.
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- Award ID(s):
- 2122399
- PAR ID:
- 10428949
- Date Published:
- Journal Name:
- Nature Communications
- Volume:
- 14
- Issue:
- 1
- ISSN:
- 2041-1723
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript
- Journal Article:
- https://doi.org/10.1038/s41467-023-36326-1
