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Title: Introduction of a (Ph 3 P) 2 Pt group into the rim of an open-cage fullerene by breaking a carbon–carbon bond
Treatment of an open-cage fullerene, designated as MMK-9, with (Ph 3 P) 4 Pt in toluene solution at room temperature allows a (PPh 3 ) 2 Pt unit to be incorporated into the rim of the cage so that it becomes an integral part of the carbon cage skeleton. The structure of the adduct has been determined by single crystal X-ray diffraction and reveals that the platinum atom has planar PtC 2 P 2 coordination, rather than the usual η 2 -bonding to an intact C–C double bond of the fullerene.  more » « less
Award ID(s):
1807637
PAR ID:
10431804
Author(s) / Creator(s):
; ; ; ;
Date Published:
Journal Name:
Chemical Communications
Volume:
57
Issue:
79
ISSN:
1359-7345
Page Range / eLocation ID:
10218 to 10221
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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