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1. Solubility, Diffusivity, and Permeability of HFC-32 and HFC-125 in Amorphous Copolymers of Perfluoro(butenyl vinyl ether) and Perfluoro(2,2-dimethyl-1,3-dioxole)

   https://doi.org/10.1021/acs.iecr.2c04518  

   Harders, Abby N. ; Sturd, Erin R. ; Wallisch, Luke ; Schmidt, Hannes ; Mendoza-Apodaca, Yuniva ; Corbin, David R. ; White, Whitney ; Junk, Christopher P. ; Shiflett, Mark B. ( March 2023 , Industrial & Engineering Chemistry Research)
2. Role of the Perfluoro Effect in the Selective Photochemical Isomerization of Hexafluorobenzene

   https://doi.org/10.1021/jacs.1c01506  

   Cox, Jordan M. ; Bain, Matthew ; Kellogg, Michael ; Bradforth, Stephen E. ; Lopez, Steven A. ( May 2021 , Journal of the American Chemical Society)

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3. Dual oxidase/oxygenase reactivity and resonance Raman spectra of {Cu 3 O 2 } moiety with perfluoro- t -butoxide ligands

   https://doi.org/10.1039/c9dt00516a  

   Brazeau, Sarah E. ; Norwine, Emily E. ; Hannigan, Steven F. ; Orth, Nicole ; Ivanović-Burmazović, Ivana ; Rukser, Dieter ; Biebl, Florian ; Grimm-Lebsanft, Benjamin ; Praedel, Gregor ; Teubner, Melissa ; et al ( May 2019 , Dalton Transactions)

   A Cu( i ) fully fluorinated O-donor monodentate alkoxide complex, K[Cu(OC 4 F 9 ) 2 ], was previously shown to form a trinuclear copper–dioxygen species with a {Cu 3 (μ 3 -O) 2 } core, T OC4F9 , upon reactivity with O 2 at low temperature. Herein is reported a significantly expanded kinetic and mechanistic study of T OC4F9 formation using stopped-flow spectroscopy. The T OC4F9 complex performs catalytic oxidase conversion of hydroquinone (H 2 Q) to benzoquinone (Q). T OC4F9 also demonstrated hydroxylation of 2,4-di- tert -butylphenolate (DBP) to catecholate, making T OC4F9 the first trinuclear species to perform tyrosinase (both monooxygenase and oxidase) chemistry. Resonance Raman spectra were also obtained for T OC4F9 , to our knowledge, the first such spectra for any T species. The mechanism and substrate reactivity of T OC4F9 are compared to those of its bidentate counterpart, T pinF , formed from K[Cu(pin F )(PR 3 )]. The monodentate derivative has both faster initial formation and more diverse substrate reactivity. 

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4. Investigations on the Synthesis, Reactivity, and Properties of Perfluoro‐α‐Benzo‐Fused BOPHY Fluorophores

   https://doi.org/10.1002/chem.202200421  

   Zhang, Guanyu ; Wang, Maodie ; Bobadova‐Parvanova, Petia ; Fronczek, Frank R. ; Smith, Kevin M. ; Vicente, M. Graça H. ( May 2022 , Chemistry – A European Journal)

   The synthesis and reactivity of 3,8‐dibromo‐dodecafluoro‐benzo‐fused BOPHY2are reported, via S_NAr with O‐, N‐ S‐ and C‐nucleophiles, and in Pd(0)‐catalyzed cross‐coupling reactions (Suzuki and Stille). The resulting perfluoro‐BOPHY derivatives were investigated for their reactivity in the presence of various nucleophiles. BOPHY3displays reversible color change and fluorescence quenching in the presence of bases (Et₃N, DBU), whereas BOPHY7reacts preferentially at the α‐pyrrolic positions, and BOPHY8undergoes regioselective fluorine substitution in the presence of thiols. The structural and electronic features of the fluorinated BOPHYs were studied by TD‐DFT computations. In addition, their spectroscopic and cellular properties were investigated; BOPHY10shows the most red‐shifted absorption/emission (λ_max659/699 nm) and7the highest fluorescence (Φ_f=0.95), while all compounds studied showed low cytotoxicity toward human HEp2 cells and were efficiently internalized.

    

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