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1. Microscopic Mechanisms of N ₂ O ₅ Hydrolysis on the Surface of Water Droplets

   https://doi.org/10.1021/acs.jpca.9b08900  

   Rossich Molina, Estefanía; Gerber, R. Benny (December 2019, The Journal of Physical Chemistry A)
2. Stability of the Y ₂ O ₃ –SiO ₂ system in high‐temperature, high‐velocity water vapor

   https://doi.org/10.1111/jace.16915  

   Parker, Cory G; Opila, Elizabeth J (April 2020, Journal of the American Ceramic Society)

   Abstract High‐temperature, high‐velocity water vapor (steam‐jet) exposures were conducted on Y₂O₃, Y₂SiO₅, Y₂Si₂O₇, and SiO₂for 60 hours at 1400°C. Volatility of Y₂O₃was not observed. Phase‐pure Y₂SiO₅exhibited SiO₂loss forming Y₂O₃and porosity. A mixed porous and dense Y₂SiO₅layer formed on the surface of Y₂Si₂O₇due to SiO₂depletion. The mechanisms and kinetics of the reaction between SiO₂and H₂O(g) to form Si(OH)₄(g) from Y₂SiO₅, Y₂Si₂O₇, and SiO₂are discussed. 

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3. The Restructuring-Induced CoO _x Catalyst for Electrochemical Water Splitting

   https://doi.org/10.1021/jacsau.1c00346  

   Wang, Maoyu; Wa, Qingbo; Bai, Xiaowan; He, Zuyun; Samarakoon, Widitha S.; Ma, Qing; Du, Yingge; Chen, Yan; Zhou, Hua; Liu, Yuanyue; et al (November 2021, JACS Au)
4. Is the Reaction Rate Coefficient for OH + HO ₂ → H ₂ O + O ₂ Dependent on Water Vapor?

   https://doi.org/10.1021/jacsau.4c00905  

   Brune, William_H; Jenkins, Jena_M (November 2024, JACS Au)
5. On the Role of Interfacial Water Dynamics for Electrochemical Stability of RuO ₂ and IrO ₂

   https://doi.org/10.1002/cctc.202200932  

   Evazzade, Iman; Zagalskaya, Alexandra; Alexandrov, Vitaly (October 2022, ChemCatChem)

   Abstract Based on the coincident onsets of oxygen evolution reaction (OER) and metal dissolution for many metal‐oxide catalysts it was suggested that OER triggers dissolution. It is believed that both processes share common intermediates, yet exact mechanistic details remain largely unknown. For example, there is still no clear understanding as to why rutile IrO₂exhibits such an exquisite stability among water‐splitting electrocatalysts. Here, we employ density functional theory calculations to analyze interactions between water and the (110) surface of rutile RuO₂and IrO₂as a response to oxygen evolution involving lattice oxygen species. We observe that these oxides display qualitatively different interfacial behavior that should have important implications for their electrochemical stability. Specifically, it is found that IrO₂(110) becomes further stabilized under OER conditions due to the tendency to form highly stable low oxidation state Ir(III) species. In contrast, Ru species at RuO₂(110) are prone to facile reoxidation by solution water. This should facilitate the formation of high Ru oxidation state intermediates (>IV) accelerating surface restructuring and metal dissolution. 

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