Metal Oxide Particles as Atmospheric Nuclei: Exploring the Role of Metal Speciation in Heterogeneous Efflorescence and Ice Nucleation
- Award ID(s):
- 1925191
- PAR ID:
- 10436513
- Date Published:
- Journal Name:
- ACS Earth and Space Chemistry
- Volume:
- 7
- Issue:
- 4
- ISSN:
- 2472-3452
- Page Range / eLocation ID:
- 812 to 822
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract Metal–organic frameworks (MOFs) are crystalline, 2‐ and 3‐dimensional coordination polymers formed by bonding interactions between metals and multitopic organic ligands. These are typically formed using hard Lewis basic organic ligands with high oxidation state metal ions. The use of low‐valent metals as structural elements in MOFs is far less common, despite the widespread use of such metals for catalysis, luminescence, and other applications. This Minireview focuses on recent advances in the field of low‐valent MOFs and offers a perspective on the future development of these materials.more » « less
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