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1. Consecutive C–H and O ₂ Activation at a Pt(II) Center To Produce Pt(IV) Aryls

   https://doi.org/10.1021/acs.organomet.8b00662  

   Watts, David; Zavalij, Peter Y.; Vedernikov, Andrei N. (November 2018, Organometallics)
2. Comparison of two Mn ^IV Mn ^IV -bis-μ-oxo complexes {[Mn ^IV (N ₄ (6-Me-DPEN))] ₂ (μ-O) ₂ } ²⁺ and {[Mn ^IV (N ₄ (6-Me-DPPN))] ₂ (μ-O) ₂ } ²⁺

   https://doi.org/10.1107/S2056989020004557  

   Coggins, Michael K.; Downing, Alexandra N.; Kaminsky, Werner; Kovacs, Julie A. (July 2020, Acta Crystallographica Section E Crystallographic Communications)

   null (Ed.)

   The addition of tert -butyl hydroperoxide ( t BuOOH) to two structurally related Mn II complexes containing N,N -bis(6-methyl-2-pyridylmethyl)ethane-1,2-diamine (6-Me-DPEN) and N,N -bis(6-methyl-2-pyridylmethyl)propane-1,2-diamine (6-Me-DPPN) results in the formation of high-valent bis-oxo complexes, namely di-μ-oxido-bis{[ N , N -bis(6-methyl-2-pyridylmethyl)ethane-1,2-diamine]manganese(II)}( Mn — Mn ) bis(tetraphenylborate) dihydrate, [Mn(C 16 H 22 N 4 ) 2 O 2 ](C 24 H 20 B) 2 ·2H 2 O or {[Mn IV (N 4 (6-Me-DPEN))] 2 ( μ -O) 2 }(2BPh 4 )(2H 2 O) ( 1 ) and di-μ-oxido-bis{[ N , N -bis(6-methyl-2-pyridylmethyl)propane-1,3-diamine]manganese(II)}( Mn — Mn ) bis(tetraphenylborate) diethyl ether disolvate, [Mn(C 17 H 24 N 4 ) 2 O 2 ](C 24 H 20 B) 2 ·2C 4 H 10 O or {[Mn IV (N 4 (6-MeDPPN))] 2 ( μ -O) 2 }(2BPh 4 )(2Et 2 O) ( 2 ). Complexes 1 and 2 both contain the `diamond core' motif found previously in a number of iron, copper, and manganese high-valent bis-oxo compounds. The flexibility in the propyl linker in the ligand scaffold of 2 , as compared to that of the ethyl linker in 1 , results in more elongated Mn—N bonds, as one would expect. The Mn—Mn distances and Mn—O bond lengths support an Mn IV oxidation state assignment for the Mn ions in both 1 and 2 . The angles around the Mn centers are consistent with the local pseudo-octahedral geometry. 

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3. CH ₃ –X Reductive Elimination Reactivity of Pt ^IV Me Complexes Supported by a Sulfonated CNN Pincer Ligand (X = OH, CF ₃ CO ₂ , PhNMe ₂ ⁺ )

   https://doi.org/10.1021/acs.organomet.9b00702  

   Ruan, Jiaheng; Wang, Daoyong; Vedernikov, Andrei N. (December 2019, Organometallics)
4. The factorisation property of l ^∞ ( X_k )

   https://doi.org/10.1017/s0305004120000304  

   LECHNER, RICHARD; MOTAKIS, PAVLOS; MÜLLER, PAUL F.X.; SCHLUMPRECHT, THOMAS (September 2021, Mathematical Proceedings of the Cambridge Philosophical Society)

   Abstract In this paper we consider the following problem: let X k , be a Banach space with a normalised basis ( e (k, j) ) j , whose biorthogonals are denoted by $${(e_{(k,j)}^*)_j}$$ , for $$k\in\N$$ , let $$Z=\ell^\infty(X_k:k\kin\N)$$ be their l ∞ -sum, and let $$T:Z\to Z$$ be a bounded linear operator with a large diagonal, i.e. , $$\begin{align*}\inf_{k,j} \big|e^*_{(k,j)}(T(e_{(k,j)})\big|>0.\end{align*}$$ Under which condition does the identity on Z factor through T ? The purpose of this paper is to formulate general conditions for which the answer is positive. 

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5. A Linear Metallocene of Sc(II) Supported by [C ₅ Me ₄ (SiMe ₂ ^t Bu)] ^1– Ligands

   https://doi.org/10.1021/jacs.5c07237  

   Nguyen, Joseph Q; Rajabi, Ahmadreza; Wang, Anthony J; Ziller, Joseph W; Furche, Filipp; Evans, William J (June 2025, Journal of the American Chemical Society)