Thermophotovoltaic (TPV) cells generate electricity by converting infrared radiation emitted by a hot thermal source. Air-bridge TPVs have demonstrated enhanced power conversion efficiencies by recuperating a large amount of power carried by below-bandgap (out-of-band) photons. Here, we demonstrate single-junction InGaAs(P) air-bridge TPVs that exhibit up to 44% efficiency under 1435°C blackbody illumination. The air-bridge design leads to near-unity reflectance (97-99%) of out-of-band photons for ternary and quaternary TPVs whose bandgaps range from 0.74 to 1.1 eV. These results suggest the applicability of the air-bridge cells to a range of semiconductor systems suitable for electricity generation from thermal sources found in both consumer and industrial applications, including thermal batteries.
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Highly Transparent, Scalable, and Stable Perovskite Solar Cells with Minimal Aesthetic Compromise
Transparent photovoltaics (TPVs) can be integrated into the surfaces of buildings and vehicles to provide point‐of‐use power without impacting aesthetics. Unlike TPVs that target the photon‐rich near‐infrared portion of the solar spectrum, TPVs that harvest ultraviolet (UV) photons can have significantly higher transparency and color neutrality, offering a superior solution for low‐power electronics with stringent aesthetic tolerance. In addition to being highly transparent and colorless, an ideal UV‐absorbing TPV should also be operationally stable and scalable over large areas while still outputting sufficient power for its specified application. None of today's TPVs meet all these criteria simultaneously. Here, the first UV‐absorbing TPV is demonstrated that satisfies all four criteria by using CsPbCl2.5Br0.5as the absorber. By precisely tuning the halide ratio during thermal co‐evaporation, high‐quality large‐area perovskite films can be accessed with an ideal absorption cutoff for aesthetic performance. The resulting TPVs exhibit a record average visible transmittance of 84.6% and a color rendering index of 96.5, while maintaining an output power density of 11 W m−2under one‐sun illumination. Further, the large‐area prototypes up to 25 cm2are demonstrated, that are operationally stable with extrapolated lifetimes of >20 yrs under outdoor conditions.
more » « less- NSF-PAR ID:
- 10442201
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Energy Materials
- Volume:
- 13
- Issue:
- 33
- ISSN:
- 1614-6832
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Significance Statement Arctic cyclones (ACs) are a weather feature that can produce high winds, precipitation, and changes to sea ice cover in the Arctic. As a result, forecasting these storms accurately is important for human and economic interests in the region; however, there are currently gaps in our understanding of how ACs strengthen and persist. In this study, we explore potential links between ACs and weather features higher up in the atmosphere called tropopause polar vortices (TPVs) using computer modeling experiments. This study shows that there are important connections between the characteristics of TPVs and the development of ACs. These findings will be useful for making more accurate forecasts of future events and advancing our knowledge of how sea ice changes relate to the atmosphere.
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MXenes, a new class of 2D transition metal carbides and carbonitrides, show great promise in supercapacitors, Li‐ion batteries, fuel cells, and sensor applications. A unique combination of their metallic conductivity, hydrophilic surface, and excellent mechanical properties renders them attractive for transparent conductive electrode application. Here, a simple, scalable method is proposed to fabricate transparent conductive thin films using delaminated Ti3C2MXene flakes by spray coating. Homogenous films, 5–70 nm thick, are produced at ambient conditions over a large area as shown by scanning electron microscopy and atomic force microscopy. The sheet resistances (
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