Combinatorial gene inactivation of aldehyde dehydrogenases mitigates aldehyde oxidation catalyzed by E. coli resting cells
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null (Ed.)The Aldehyde-Water Shift (AWS) reaction uses H 2 O as a benign oxidant to convert aldehydes to carboxylic acids, producing H 2 , a valuable reagent and fuel, as its sole byproduct. (Hexamethylbenzene)Ru II complexes are demonstrated to have higher activity and selectivity (up to 95%) for AWS over disproportionation than previously reported catalysts.more » « less