Passive daytime radiative cooling (PDRC) involves spontaneously cooling a surface by reflecting sunlight and radiating heat to the cold outer space. Current PDRC designs are promising alternatives to electrical cooling but are either inefficient or have limited applicability. We present a simple, inexpensive, and scalable phase inversion–based method for fabricating hierarchically porous poly(vinylidene fluoride-co-hexafluoropropene) [P(VdF-HFP)HP] coatings with excellent PDRC capability. High, substrate-independent hemispherical solar reflectances (0.96 ± 0.03) and long-wave infrared emittances (0.97 ± 0.02) allow for subambient temperature drops of ~6°C and cooling powers of ~96 watts per square meter (W m−2) under solar intensities of 890 and 750 W m−2, respectively. The performance equals or surpasses those of state-of-the-art PDRC designs, and the technique offers a paint-like simplicity.
Passive daytime radiative cooling (PDRC) can realize electricity‐free cooling by reflecting sunlight and emitting heat to the cold space. Current PDRC designs often involve costly vacuum processing or a large quantity of harmful organic solvents. Aqueous and paint‐like processing is cost‐effective and environmentally benign, thereby highly attractive for green manufacturing of PDRC coatings. However, common polymers explored in PDRC are difficult to disperse in water, let alone forming porous structures for efficient cooling. Here, a simple “bottom‐up” ball milling approach to create uniform microassembly of poly(vinylidene fluoride‐
- Award ID(s):
- 2005747
- PAR ID:
- 10452974
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Functional Materials
- Volume:
- 31
- Issue:
- 19
- ISSN:
- 1616-301X
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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