Photoelectron spectroscopy and quantum chemistry studies are used to investigate the structure and bonding of AuB 8 − . Global minimum sturctural searches show that AuB 8 − possesses a chair-like structure, which can be viewed as Au + bonded to the edge of the doubly-aromatic B 8 2− borozene, Au + [η 2 -B 8 2− ]. Chemical bonding analyses reveal that the AuB 8 − is a novel borozene complex with unique Au–borozene bonding.
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Direct Reduction of NO to N 2 O by a Mononuclear Nonheme Thiolate Ligated Iron(II) Complex via Formation of a Metastable {FeNO} 7 Complex
- Award ID(s):
- 1955527
- PAR ID:
- 10465500
- Date Published:
- Journal Name:
- Inorganic Chemistry
- Volume:
- 61
- Issue:
- 38
- ISSN:
- 0020-1669
- Page Range / eLocation ID:
- 14909 to 14917
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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