The effect of initial microstructure and its evolution across the α→ω phase transformation in commercially pure Zr under hydrostatic compression has been studied using in situ x-ray diffraction measurements. Two samples were studied: one is plastically pre-deformed Zr with saturated hardness and the other is annealed. Phase transformation α→ω initiates at lower pressure for pre-deformed sample, suggesting pre-straining promotes nucleation by producing more defects with stronger stress concentrators. With transformation progress, the promoting effect on nucleation reduces while that on growth is suppressed by producing more obstacles for interface propagation. The crystal domain size reduces and microstrain and dislocation density increase during loading for both α and ω phases in their single-phase regions. For α phase, domain sizes are much smaller for prestrained Zr, while microstrain and dislocation densities are much higher. On the other hand, they do not differ much in ω Zr for both prestrained and annealed samples, implying that microstructure is not inherited during phase transformation. The significant effect of pressure on the microstructural parameters (domain size, microstrain, and dislocation density) demonstrates that their postmortem evaluation does not represent the true conditions during loading. A simple model for the initiation of the phase transformation involving microstrain is suggested, and a possible model for the growth is outlined. The obtained results suggest an extended experimental basis is required for better predictive models for the pressure-induced and combined pressure- and strain-induced phase transformations.
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This content will become publicly available on May 1, 2024
Short-range-ordering strengthening and the evolution of dislocation-nucleation modes in an Fe40Mn20Cr20Ni20 high-entropy alloy
Compared with the Fe40Mn20Cr20Ni20 high-entropy alloy in an homogenized state, it has higher incipient plastic strength after high-temperature aging, which is attributed to the generation of short-range orderings (SROs) caused by the local composition fluctuations. Based on nanoindentation results at different loading rates, the evolution trends of homogeneous and heterogeneous dislocation-nucleation modes under the effect of SROs are revealed for the first time. Under the action of the high-solution friction stress, which is caused by the high loading rate, and coherency-strain field, which is caused by SROs, the critical shear stress of the dislocation nucleation increases. Furthermore, with the increase of the loading rate, the probability of heterogeneous nucleation in homogenized samples increases, while that in aged samples is the opposite. From the perspective of the distribution of dislocation-nucleation sites, this opposite trend can be well explained by assuming the spreading resistance of an activatable region. In short, the present work reveals the pivotal role of SROs on dislocation-nucleation modes and paves the way for the quantitative study concerning SROs and their strengthening effects.
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- Award ID(s):
- 2226495
- NSF-PAR ID:
- 10472126
- Publisher / Repository:
- Elsevier
- Date Published:
- Journal Name:
- Materials Science and Engineering: A
- Volume:
- 873
- Issue:
- C
- ISSN:
- 0921-5093
- Page Range / eLocation ID:
- 145038
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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