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Title: A Real‐Time Process Diagnostic to Support Reliability, Control, and Fundamental Understanding in Aerosol Jet Printing

Aerosol jet printing is a compelling technology for hybrid electronics, combining digital and noncontact patterning with broad materials compatibility, resolution as fine as ≈10 microns, and a high standoff distance of 1–5 mm. Despite its growing popularity in research environments, a robust process understanding and improved manufacturing control are essential for achieving the reliability and predictability required for broader adoption in advanced applications. Herein, recent developments in process monitoring using in‐line light scattering measurements are discussed, including their mechanistic foundations, experimental validation, relevance for process control and reliability, and value as a diagnostic tool for fundamental studies. Experimental measurements confirm the correlation between measured light scattering and deposition rate. Building on this platform, feedback from the real‐time measurement is coupled with printer software to support automated closed‐loop control via a simple proportional‐integral‐derivative software control loop. Combined with the utility of these measurements as a diagnostic to accelerate ink formulation and support fundamental process science experiments, this in‐line measurement provides a useful tool to improve print reliability with the potential to advance the adoption and capabilities of this method in conformal, flexible, and hybrid electronics applications.

 
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NSF-PAR ID:
10473598
Author(s) / Creator(s):
 ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
Advanced Engineering Materials
Volume:
26
Issue:
1
ISSN:
1438-1656
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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    Acknowledgement

    This work was supported by the U.S. National Science Foundation (NSF) Award No. ECCS-1931088. S.L. and H.W.S. acknowledge the support from the Improvement of Measurement Standards and Technology for Mechanical Metrology (Grant No. 22011044) by KRISS.

    References

    [1] Younget al.,IEEE Computational Intelligence Magazine,vol. 13, no. 3, pp. 55-75, 2018.

    [2] Hadsellet al.,Journal of Field Robotics,vol. 26, no. 2, pp. 120-144, 2009.

    [3] Najafabadiet al.,Journal of Big Data,vol. 2, no. 1, p. 1, 2015.

    [4] Zhaoet al.,Applied Physics Reviews,vol. 7, no. 1, 2020.

    [5] Zidanet al.,Nature Electronics,vol. 1, no. 1, pp. 22-29, 2018.

    [6] Wulfet al.,SIGARCH Comput. Archit. News,vol. 23, no. 1, pp. 20–24, 1995.

    [7] Wilkes,SIGARCH Comput. Archit. News,vol. 23, no. 4, pp. 4–6, 1995.

    [8] Ielminiet al.,Nature Electronics,vol. 1, no. 6, pp. 333-343, 2018.

    [9] Changet al.,Nano Letters,vol. 10, no. 4, pp. 1297-1301, 2010.

    [10] Qinet al., Physica Status Solidi (RRL) - Rapid Research Letters, pssr.202200075R1, In press, 2022.

     
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