Antimony selenide (Sb2Se3) emerges as a promising sunlight absorber in thin film photovoltaic applications due to its excellent light absorption properties and carrier transport behavior, attributed to the quasi‐one‐dimensional Sb4Se6‐nanoribbon crystal structure. Overcoming the challenge of aligning Sb2Se3‐nanoribbons normal to substrates for efficient photogenerated carrier extraction, a solution‐processed nanocrystalline Sb2(S,Se)3‐seeds are employed on the CdS buffer layer. These seeds facilitate superstrated Sb2Se3thin film solar cell growth through a close‐space sublimation approach. The Sb2(S,Se)3‐seeds guided the Sb2Se3absorber growth along a [002]‐preferred crystal orientation, ensuring a smoother interface with the CdS window layer. Remarkably, Sb2(S,Se)3‐seeds improve carrier transport, reduce series resistance, and increase charge recombination resistance, resulting in an enhanced power conversion efficiency of 7.52%. This cost‐effective solution‐processed seeds planting approach holds promise for advancing chalcogenide‐based thin film solar cells in large‐scale manufacturing.
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Post‐Annealing Treatment on Hydrothermally Grown Antimony Sulfoselenide Thin Films for Efficient Solar Cells
Herein, antimony sulfoselenide (Sb2(S, Se)3) thin‐film solar cells are fabricated by a hydrothermal method followed by a post‐deposition annealing process at different temperatures and the impact of the annealing temperature on the morphological, structural, optoelectronic, and defect properties of the hydrothermally grown Sb2(S, Se)3films is investigated. It is found that a proper annealing temperature leads to high‐quality Sb2(S, Se)3films with large crystal grains, high crystallinity, preferred crystal orientation, smooth and uniform morphology, and reduced defect density. These results show that suppressing deep‐level defects is crucial to enhance solar cell performance. After optimizing the annealing process, Sb2(S, Se)3solar cells with an improved power conversion efficiency 2.04 to 8.48% are obtained.
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- Award ID(s):
- 1950785
- PAR ID:
- 10479611
- Publisher / Repository:
- Wiley-VCH GmbH
- Date Published:
- Journal Name:
- Solar RRL
- Volume:
- 7
- Issue:
- 4
- ISSN:
- 2367-198X
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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