Abstract Deception Island is one of the most active volcanoes in Antarctica with more than twenty explosive eruptions in the past two centuries. Any future volcanic eruption(s) is a serious concern for scientists and tourists, will be detrimental to marine ecosystems and could have an impact to global oceanographic processes. Currently, it is not possible to carry-out low and high frequency volcanic gas monitoring at Deception Island because of the arduous climatic conditions and its remote location. Helium, neon and argon isotopes measured in olivine samples of the main eruptive events (pre-, syn- and post caldera) offer insights into the processes governing its volcanic history. Our results show that: (i) ascending primitive magmas outgassed volatiles with a MORB-like helium isotopic signature ( 3 He/ 4 He ratio); and (ii) variations in the He isotope ratio, as well as intensive degassing evidenced by fractionated 4 He/ 40 Ar * values, occurred before the beginning of the main eruptive episodes. Our results show how the pre-eruptive noble gas signals of volcanic activity is an important step toward a better understanding of the magmatic dynamics and has the potential to improve eruption forecasting.
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Constraining the volatile evolution of mafic melts at Mt. Somma–Vesuvius, Italy, based on the composition of reheated melt inclusions and their olivine hosts
Abstract. Mount Somma–Vesuvius is a stratovolcano that represents a geological hazard to the population of the city of Naples and surrounding towns in southern Italy. Historically, volcanic eruptions at Mt. Somma–Vesuvius (SV) include high-magnitude Plinian eruptions, such as the infamous 79 CE eruption that occurred after 295 years of quiescence and killed thousands of people in Pompeii and surrounding towns and villages. The last eruption at SV was in 1944 and showed a Volcanic Explosivity Index (VEI) of 3 (0.01 km3 of volcanic material erupted). Following the 1944 eruption, SV has been dormant for the past nearly 79 years, with only minor fumarolic and seismic activity. During its long history, centuries of dormancy at SV have ended with Plinian eruptions (VEI 6) that signal the beginning of a new cycle of eruptive activity. Thus, the current dormancy stage demands a need to better understand the mechanism involved in high-magnitude eruptions in order to better predict future eruption magnitude and style. Despite centuries of research on the SV volcanic system, many questions remain, including the evolution of magmatic volatiles from deep primitive magmas to shallower more evolved magmas. Developing a better understanding of the physical and chemical processes associated with volatile evolution at SV can provide insights into magma dynamics and the mechanisms that trigger highly explosive eruptions at SV. In this study, we present new data for the pre-eruptive volatile contents of magmas associated with four Plinian and two inter-Plinian eruptions at SV based on analyses of reheated melt inclusions (MIs) hosted in olivine. We correct the volatile contents of bubble-bearing MIs by taking into account the volatile contents of bubbles in the MIs. We recognize two groups of MIs: one group hosted in high-Fo olivine (Fo85–90) and relatively rich in volatiles and the other group hosted in low-Fo olivine (Fo70–69) and relatively depleted in volatiles. The correlation between volatile contents and compositions of host olivines suggests that magma fractionation took place under volatile-saturated conditions and that more differentiated magmas reside at shallower levels relative to less evolved/quasi-primitive magmas. Using the CO2 contents of corrected MIs hosted in Fo90 olivine from SV, we estimate that 347 to 686 t d−1 of magmatic CO2 exsolved from SV magmas during the last 3 centuries (38–75 Mt in total) of volcanic activity. Although this study is limited to only few SV magmas, we suggest that further study applying similar methods could shed light on the apparent lack of correlation between the volatile contents of MIs and the style and age of eruptions. Further, such studies could provide additional constraints on the origin of CO2 and the interaction between the carbonate platform and ascending magmas below SV.
more » « less- Award ID(s):
- 2124650
- NSF-PAR ID:
- 10484767
- Publisher / Repository:
- European Journal of Mineralogy
- Date Published:
- Journal Name:
- European Journal of Mineralogy
- Volume:
- 35
- Issue:
- 6
- ISSN:
- 1617-4011
- Page Range / eLocation ID:
- 921 to 948
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract Cerro Machín, a volcano located in the northern segment of the Andes, is considered one of the most dangerous volcanoes in Colombia with an explosive record that involves at least five plinian events. Prior studies focused on the last dome-building eruption have suggested the presence of a water-rich mid-crustal magma reservoir. However, no direct volatile measurements have been published and little work has been completed on the explosive products of the volcano. Here, we study the largest known eruption of Cerro Machín volcano which occurred 3600 years BP producing dacitic pyroclastic fall deposits that can be traced up to 40 km from the vent. Lapilli pumice clasts have a mineral assemblage of plagioclase, amphibole, quartz, and biotite phenocrysts, with accessory olivine, Fe–Ti oxides, and apatite. The occurrence of Fo89–92 olivine rimmed by high Mg# amphibole and the established high-water contents in the magma imply the presence of magma near or at water saturation at pressures > ~ 500 MPa. Measurements of up to 10.7 wt % H2O in melt inclusions hosted in plagioclase and quartz in the 3600 years BP eruption products support the idea that Cerro Machín is a remarkably water-rich volcanic system. Moreover, this is supported by measurements of ~103 to 161 ppm H2O in plagioclase phenocrysts. The application of two parameterizations of water partitioning between plagioclase and silicate melt allows us to use our water in plagioclase measurements to estimate equilibrium melt water contents of 5 ± 1 wt % to 11 ± 2 wt % H2O, which are in good agreement with the water contents we measured in melt inclusions. Results of amphibole geobarometry are consistent with a magma reservoir stored in the mid-to-lower crust at a modal pressure of 700 ± 250 MPa, corresponding to a depth of ~25 km. Minor crystallization in the shallow crust is also recorded by amphibole barometry and calculated entrapment pressures in melt inclusions. Amphibole is present as unzoned and zoned crystals. Two populations of unzoned amphibole crystals are present, the most abundant indicate crystallization conditions of 853 ± 26°C (1 se; standard error), and the less abundant crystallized at an average temperature of 944 ± 24°C (1 se). Approximately 18% of the amphibole crystals are normally or reversely zoned, providing evidence for a minor recharge event that could have been the trigger mechanism for the explosive eruption. Plagioclase crystals also show normal and reverse zoning. The moderate Ni concentrations (<1600 μg/g) in the high-Fo olivine xenocrysts suggest that Cerro Machín primary magmas are generated by inefficient interaction of mantle peridotite with a high-silica melt produced by slab melting of basaltic material. Some sediment input is also suggested by the high Pb/Th (>2.2) and Th/La (0.3–0.4) ratios. Whole rock chemistry reveals heavy rare earth element (HREE) depletion and Sr enrichment that likely formed during the crystallization of garnet and amphibole in the upper part of the mantle or lower portion of the crust, promoting the formation of water-rich dacitic magma that was then injected into the middle-to-lower crust. Textural and compositional differences in the crystal cargo that erupted during dome-building and plinian events support the idea that large volumes of magma recharge lead to effusive eruptions, while only small recharge events are needed to trigger plinian eruptions at Cerro Machín.
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Abstract Recharges of magma underneath basaltic volcanoes can occur as precursory events prior to an eruption but are not always revealed in geophysical data streams or erupted lavas compositions. In contrast, phosphorus within primitive, Mg‐rich (Fo89‐90), olivine can preserve recharge information lost by the mixed melt. Evidence of rapid growth and dissolution are preserved only in phosphorus X‐ray intensity maps, which reveal that Mg‐rich olivine from eruptions occurring between 2008 and 2020 at Kīlauea Volcano (Hawaiʻi) experienced at least two episodes of magma intrusion. We develop numerical diffusion models that evaluate the fidelity of the Fe‐Mg compositional archive by quantifying three factors that influence Fo population distributions: (a) the frequency at which an Mg‐rich basaltic liquid (in equilibrium with Fo90olivine) intrudes the reservoir, (b) the pre‐existence of a polymodal distribution of olivine crystal sizes and their shapes (c) the effects of sectioning on apparent olivine core compositions. We find that most crystals lose their initial Mg‐rich composition if they are held at temperatures relevant to summit magma storage conditions (1,160–1,190°C) for more than 10 years. Thus, previous assertions that Mg‐rich olivine crystals at Kīlauea are scavenged from centuries‐old stored magmas are unrealistic. Our method permits critical evaluation of contrasting explanations of heterogeneous Fe‐Mg contents of olivine cargo: (a) different total durations of mush storage with partial diffusive erasure of compositional traits, or (b) coexistence of multiple chemically distinct magmas. Our approach provides general guidance for the conservative interpretation of temporal information preserved within olivine Fe‐Mg compositional archives.
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Constraining the volatile content of magmas is critical to our understanding of eruptive processes and their deep Earth cycling essential to planetary habitability [R. Dasgupta, M. M. Hirschmann, Earth Planet. Sci. Lett. 298 , 1 (2010)]. Yet, much of the work thus far on magmatic volatiles has been dedicated to understanding their cycling through subduction zones. Further, studies of intraplate mafic volcanism have disproportionately focused on Hawaii [P. E. Wieser et al., Geochem. Geophys. Geosyst. 22 , e2020GC009364 (2021)], making assessments of the overall role of intraplate volcanoes in the global volatile cycles a challenge. Additionally, while mafic volcanoes are the most common landform on Earth and the Solar System [C. A. Wood, J. Volcanol. Geotherm. Res. 7 , 387–413 (1980)], they tend to be overlooked in favor of silicic volcanoes when it comes to their potential for explosivity. Here, we report primitive (olivine-hosted, with host Magnesium number – Mg# 78 to 88%) melt inclusion (MI) data from Fogo volcano, Cabo Verde, that suggest that oceanic intraplate silica-undersaturated explosive eruptions sample volatile-rich sources. Primitive MI (melt Mg# 70 to 71%) data suggest that these melts are oxidized (NiNiO to NiNiO+1) and very high in volatiles (up to 2 wt% CO 2 , 2.8 wt% H 2 O, 6,000 ppm S, 1,900 ppm F, and 1,100 ppm Cl) making Fogo a global endmember. Storage depths calculated from these high volatile contents also imply that magma storage at Fogo occurs at mantle depths (~20 to 30 km) and that these eruptions are fed from the mantle. Our results suggest that oceanic intraplate mafic eruptions are sustained from the mantle by high volatile concentrations inherited from their source and that deep CO 2 exsolution (here up to ~800 MPa) drives their ascent and explosivity.more » « less
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Abstract Water and carbon dioxide are the most abundant volatile components in terrestrial magmas. As they exsolve into magmatic vapour, they promote magma buoyancy, accelerating ascent and modulating eruptive dynamics. It is commonly thought that an increase in pre-eruptive volatile content produces an increase in eruption intensity. Using a conduit model for basaltic eruptions, covering the upper 6 km of conduit, we show that for the same chamber conditions mass eruption rate is not affected by CO2content, whereas an increase in H2O up to 10 wt.% produces an increase in eruption rate of an order of magnitude. It is only when CO2is injected in the magma reservoir from an external source that the resulting pressurisation will generate a strong increase in eruption rate. Results also show that ascent velocity and fragmentation depth are strongly affected by pre-eruptive volatile contents demonstrating a link between volatile content and eruptive style.
- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.5194/ejm-35-921-2023
