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   Lin, Binzhou; Liu, Hao; Karki, Ishwor; Vik, Erik C.; Smith, Mark D.; Pellechia, Perry J.; Shimizu, Ken D. (May 2023, Angewandte Chemie International Edition)

   Abstract Stabilizing nitrogen pnictogen bond interactions were measured using molecular rotors. Intramolecular C=O⋅⋅⋅N interactions were formed in the bond rotation transition states which lowered the rotational barriers and increased the rates of rotation, as measured by EXSY NMR. The pnictogen interaction energies show a very strong correlation with the positive electrostatic potential on nitrogen, which was consistent with a strong electrostatic component. In contrast, the NBO perturbation and pyramidalization analyses show no correlation, suggesting that the orbital‐orbital component is minor. The strongest C=O⋅⋅⋅N pnictogen interactions were comparable to C=O⋅⋅⋅C=O interactions and were stronger than C=O⋅⋅⋅Ph interactions, when measured using the sameN‐phenylimide rotor system. The ability of the nitrogen pnictogen interactions to stabilize transition states and enhance kinetic processes demonstrates their potential in catalysis and reaction design. 

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   The electronics-centered approach to physical computing presents challenges when designers build tangible interactive systems due to its inherent emphasis on circuitry and electronic components. To explore an alternative physical computing approach we have developed a computer vision (CV) based system that uses a webcam, computer, and printed fiducial markers to create functional tangible interfaces. Through a series of design studios, we probed how designers build tangible interfaces with this CV-driven approach. In this paper, we apply the annotated portfolio method to reflect on the fifteen outcomes from these studios. We observed that CV markers offer versatile materiality for tangible interactions, afford the use of democratic materials for interface construction, and engage designers in embodied debugging with their own vision as a proxy for CV. By sharing our insights, we inform other designers and educators who seek alternative ways to facilitate physical computing and tangible interaction design. 

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   Palmer, Meredith S.; Willis, Charlie; Barry, Katherine; Packer, Craig; Moe, Annika; Wassenberg, Deena (January 2020, CourseSource)

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4. Quantum Heat Engines with Singular Interactions

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   Myers, Nathan M.; McCready, Jacob; Deffner, Sebastian (June 2021, Symmetry)

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   By harnessing quantum phenomena, quantum devices have the potential to outperform their classical counterparts. Here, we examine using wave function symmetry as a resource to enhance the performance of a quantum Otto engine. Previous work has shown that a bosonic working medium can yield better performance than a fermionic medium. We expand upon this work by incorporating a singular interaction that allows the effective symmetry to be tuned between the bosonic and fermionic limits. In this framework, the particles can be treated as anyons subject to Haldane’s generalized exclusion statistics. Solving the dynamics analytically using the framework of “statistical anyons”, we explore the interplay between interparticle interactions and wave function symmetry on engine performance. 

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