Sedimentary arsenic (As) in the shallow aquifers of Bangladesh is enriched in finer-grained deposits that are rich in organic matter (OM), clays, and iron (Fe)-oxides. In Bangladesh, sediment color is a useful indicator of pore water As concentrations. The pore waters of orange sediments are usually associated with lower As concentrations (<50 µg/L) owing to abundant Fe-oxides which sorb As. Using this color signal as a guide, spectroscopic measurements alongside thermal treatment were extensively utilized for analyzing the properties of both Fe-oxides and clay minerals. This study uses Fourier transform infrared (FTIR) and diffuse reflectance (DR) measurements along with thermal treatment to evaluate the solid-phase associations of As from sediment collected along the Meghna River in Bangladesh. The samples analyzed in this study were chosen to represent the various lithologies present at the study site and included riverbank sands (1 m depth), silt (6 m depth), aquifer sand (23 m depth), and a clay aquitard (37 m depth). The concentrations of sedimentary As and Fe were measured by X-ray fluorescence, and the spectroscopic measurements were taken on the samples prior to the thermal treatment. For the thermal treatment, sediment samples were placed in a preheated furnace at 600 °C for 3 h. The thermal treatment caused a deepening of reddish-brown hues in all samples, and the greatest change in color was observed in the finer-grained samples. The FTIR spectral analysis revealed that the clay minerals were composed primarily of illite, smectite, and kaolinite. The DR results indicate that the majority of Fe in sands was present as goethite; however, in the clay and silt samples, Fe was incorporated into the structure of clay minerals as Fe(II). The amount of structural Fe(II) was strongly positively correlated with the sedimentary As concentrations, which were highest in the finer-grained samples. After thermal treatment, the concentrations of As in the finer-grained samples decreased by an average of 40%, whereas the change in the As concentrations of the sand samples was negligible. These findings indicate that significant proportions of solid-phase As may be retained by OM and Fe(II)-bearing clay minerals.
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This content will become publicly available on September 1, 2024
Mineralogical Associations of Sedimentary Arsenic within a Contaminated Aquifer Determined through Thermal Treat-ment and Spectroscopy
Sedimentary arsenic (As) in the shallow aquifers of Bangladesh is enriched in finer-grained de-posits rich in organic matter, clays, and iron (Fe)-oxides. In Bangladesh, sediment color is a use-ful indicator of pore-water As concentrations. The pore-waters of orange sediments are usually associated with lower As concentrations (<50 µg/L) owing to abundant Fe-oxides which sorb As. Using this color signal as a guide, spectroscopic measurements alongside thermal treatment have been extensively utilized for analyzing the properties of both Fe-oxides and clay minerals. This study uses Fourier transform infrared (FTIR) and diffuse reflectance (DR) measurements along with thermal treatment to evaluate the solid-phase associations of As from sediment col-lected along the Meghna River in Bangladesh. The samples analyzed in this study were chosen to represent the various lithologies present at the study site and included riverbank sands (1 m depth), silt (6 m depth), aquifer sand (23 m depth), and a clay aquitard (37 m depth). The concen-trations of sedimentary As and Fe were measured by X-Ray Fluorescence and the spectroscopic measurements were taken on the samples prior to the thermal treatment. For the thermal treat-ment, sediment samples were placed in a preheated furnace at 600C for 3 hours. The thermal treatment caused a deepening of reddish-brown hues in all samples, and the greatest change of color was observed in the finer-grained samples. The FTIR spectral analysis revealed that the clay minerals were composed primarily of illite, smectite, and kaolinite. The DR results indicat-ed that the majority of Fe in sands was present as goethite; however, in the clay and silt samples, Fe was incorporated into the structure of clay minerals as Fe(II). The amount of structural Fe(II) was strongly positively correlated with the sedimentary As concentrations, which were highest in the finer-grained samples. After thermal treatment, the concentrations of As in the finer-grained samples decreased by an average of 40% whereas the change in the As concentrations of the sand samples was negligible. These findings indicate that significant proportions of solid-phase As may be retained by OM and Fe(II)-bearing clay minerals.
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- Award ID(s):
- 1852652
- NSF-PAR ID:
- 10495861
- Publisher / Repository:
- Minerals
- Date Published:
- Journal Name:
- Minerals
- ISSN:
- 2075-163X
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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null (Ed.)The Nankai Trough Seismogenic Zone Experiment (NanTroSEIZE) is a coordinated, multiexpedition International Ocean Discovery Program (IODP) drilling project designed to investigate fault mechanics and seismogenesis along subduction megathrusts through direct sampling, in situ measurements, and long-term monitoring in conjunction with allied laboratory and numerical modeling studies. The fundamental scientific objectives of the NanTroSEIZE drilling project include characterizing the nature of fault slip and strain accumulation, fault and wall rock composition, fault architecture, and state variables throughout the active plate boundary system. IODP Expedition 365 is part of NanTroSEIZE Stage 3, with the following primary objectives: (1) retrieval of a temporary observatory at Site C0010 that has been monitoring temperature and pore pressure within the major splay thrust fault (termed the “megasplay”) at 400 meters below seafloor since November 2010 and (2) deployment of a complex long-term borehole monitoring system (LTBMS) that will be connected to the Dense Oceanfloor Network System for Earthquakes and Tsunamis (DONET) seafloor cabled observatory network postexpedition (anticipated June 2016). The LTBMS incorporates multilevel pore pressure sensing, a volumetric strainmeter, tiltmeter, geophone, broadband seismometer, accelerometer, and thermistor string. Together with an existing observatory at Integrated Ocean Drilling Program Site C0002 and a possible future installation near the trench, the Site C0010 observatory will allow monitoring within and above regions of contrasting behavior of the megasplay fault and the plate boundary as a whole. These include a site above the updip edge of the locked zone (Site C0002), a shallow site in the megasplay fault zone and its footwall (Site C0010), and a site at the tip of the accretionary prism (Integrated Ocean Drilling Program Site C0006). Together, this suite of observatories has the potential to capture deformation spanning a wide range of timescales (e.g., seismic and microseismic activity, slow slip, and interseismic strain accumulation) across a transect from near-trench to the seismogenic zone. Site C0010 is located 3.5 km along strike to the southwest of Integrated Ocean Drilling Program Site C0004. 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The pressure records from the GeniusPlug include high-quality records of formation and seafloor responses to multiple fault slip events, including the 11 March 2011 Tohoku M9 and 1 April 2016 Mie-ken Nanto-oki M6 earthquakes. The geochemical sampling coils yielded in situ pore fluids from the splay fault zone, and microbes were successfully cultivated from the colonization unit. The complex sensor array, in combination with the multilevel hole completion, is one of the most ambitious and sophisticated observatory installations in scientific ocean drilling (similar to that in Hole C0002G, deployed in 2010). Overall, the installation went smoothly, efficiently, and ahead of schedule. The extra time afforded by the efficient observatory deployment was used for coring in Holes C0010B–C0010E. Despite challenging hole conditions, the depth interval corresponding to the screened casing across the megasplay fault was successfully sampled in Hole C0010C, and the footwall of the megasplay was sampled in Hole C0010E, with >50% recovery for both zones. In the hanging wall of the megasplay fault (Holes C0010C and C0010D), we recovered indurated silty clay with occasional ash layers and sedimentary breccias. Some of the deposits show burrows and zones of diagenetic alteration/colored patches. Mudstones show different degrees of deformation spanning from occasional fractures to intervals of densely fractured scaly claystones of up to >10 cm thickness. Sparse faulting with low displacement (usually <2 cm) is seen in core and exhibits primarily normal and, rarely, reversed sense of slip. When present, ash was entrained along fractures and faults. On one occasion, a ~10 cm thick ash layer was found, which showed a fining-downward gradation into a mottled zone with clasts of the underlying silty claystones. In Hole C0010E, the footwall to the megasplay fault was recovered. Sediments are horizontally to gently dipping and mainly comprise silt of olive-gray color. The deposits of the underthrust sediment prism are less indurated than the hanging wall mudstones and show lamination on a centimeter scale. The material is less intensely deformed than the mudstones, and apart from occasional fracturation (some of it being drilling disturbance), evidence of structural features is absent.more » « less
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null (Ed.)The Nankai Trough Seismogenic Zone Experiment (NanTroSEIZE) is a coordinated, multiexpedition International Ocean Discovery Program (IODP) drilling project designed to investigate fault mechanics and seismogenesis along subduction megathrusts through direct sampling, in situ measurements, and long-term monitoring in conjunction with allied laboratory and numerical modeling studies. The fundamental scientific objectives of the NanTroSEIZE drilling project include characterizing the nature of fault slip and strain accumulation, fault and wall rock composition, fault architecture, and state variables throughout the active plate boundary system. IODP Expedition 365 is part of NanTroSEIZE Stage 3, with the following primary objectives: 1. Retrieval of a temporary observatory at Site C0010 that began monitoring temperature and pore pressure within the major splay thrust fault (termed the “megasplay”) at 400 meters below seafloor in November 2010. 2. Deployment of a complex long-term borehole monitoring system (LTBMS) designed to be connected to the Dense Oceanfloor Network System for Earthquakes and Tsunamis (DONET) seafloor cabled observatory network postexpedition. The LTBMS incorporates multilevel pore pressure sensing, a volumetric strainmeter, tiltmeter, geophone, broadband seismometer, accelerometer, and thermistor string. Together with an existing observatory at Integrated Ocean Drilling Program Site C0002 and a planned future installation near the trench, the Site C0010 observatory allows monitoring within and above regions of contrasting behavior of the megasplay fault and the plate boundary as a whole. These include a site above the updip edge of the locked zone (Site C0002), a shallow site in the megasplay fault zone and its footwall (Site C0010), and a site at the tip of the accretionary prism (possible future installation at Integrated Ocean Drilling Program Site C0006). Together, this suite of observatories has the potential to capture deformation spanning a wide range of timescales (e.g., seismic and microseismic activity, slow slip, and interseismic strain accumulation) across a transect from near-trench to the seismogenic zone. Site C0010 is located 3.5 km along strike to the southwest of Integrated Ocean Drilling Program Site C0004. The site was drilled and cased during Integrated Ocean Drilling Program Expedition 319, with casing screens spanning a ~20 m interval that includes the megasplay fault, and suspended with a temporary instrument package (a “SmartPlug”), which included pressure and temperature sensors. During Integrated Ocean Drilling Program Expedition 332 in late 2010, the instrument package was replaced with an upgraded sensor package (the “GeniusPlug”), which included a set of geochemical and biological experiments in addition to pressure and temperature sensors. Expedition 365 achieved its primary scientific and operational objectives, including recovery of the GeniusPlug with a >5 y record of pressure and temperature conditions within the shallow megasplay fault zone, geochemical samples, and its in situ microbial colonization experiment; and installation of the LTBMS. The pressure records from the GeniusPlug include high-quality records of formation and seafloor responses to multiple fault slip events, including the 11 March 2011 Tohoku M9 and 1 April 2016 Mie-ken Nanto-oki M6 earthquakes. The geochemical sampling coils yielded in situ pore fluids from the splay fault zone, and microorganisms were successfully cultivated from the colonization unit. The complex sensor array, in combination with the multilevel hole completion, is one of the most ambitious and sophisticated observatory installations in scientific ocean drilling (similar to that in Hole C0002G, deployed in 2010). Overall, the installation went smoothly, efficiently, and ahead of schedule. The extra time afforded by the efficient observatory deployment was used for coring in Holes C0010B–C0010E. Despite challenging hole conditions, the depth interval corresponding to the screened casing across the megasplay fault was successfully sampled in Hole C0010C, and the footwall of the megasplay was sampled in Hole C0010E, with >50% recovery for both zones. In the hanging wall of the megasplay fault (Holes C0010C and C0010D), we recovered indurated silty clay with occasional ash layers and sedimentary breccias. Mudstones show different degrees of deformation spanning from occasional fractures to intervals of densely fractured scaly claystones of up to >10 cm thickness. Sparse faulting with low displacement (usually <2 cm) is seen in core and exhibits primarily normal and, rarely, reversed sense of slip. When present, ash was entrained along fractures and faults. 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