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Abstract As part of our interest in unusual bonding situations, we are now targeting complexes featuring metal→carbon dative bonds. Here, we report on the formation of such linkages in a series of Group 10 complexes featuring a triarylphosphine ligand functionalized at the γ position by a carbenium ion. Through combined synthetic, spectroscopic, and computational studies, we show that the M→Ccarbeniuminteraction present in these complexes scales with the basicity of the donor, confirming its dative nature.
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Structure and Bonding in π-Stacked Perylenes: The Impact of Charge on Pancake Bonding
- PAR ID:
- 10499156
- Publisher / Repository:
- American Chemical Society
- Date Published:
- Journal Name:
- Journal of the American Chemical Society
- Volume:
- 146
- Issue:
- 15
- ISSN:
- 0002-7863
- Format(s):
- Medium: X Size: p. 10465-10477
- Size(s):
- p. 10465-10477
- Sponsoring Org:
- National Science Foundation
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