ABSTRACT Backward erosion piping (BEP) is a significant contributor to failures in global flood protection infrastructure, yet it remains among the least understood geotechnical phenomena, particularly concerning the fundamental mechanisms driving its initiation. This study focuses on the development of a novel stochastic framework for the prediction of critical hydraulic gradients causing BEP initiation. The novelty of the study lies in the following: (1) the development of a grain‐scale probabilistic model based on fundamental mechanisms by means of the theory of rate processes, (2) quantification of the influence of soil variability on BEP initiation probability by introducing an initiation probability function, and (3) an analytical framework reconciling grain kinetics of BEP initiation with the Weibull distribution. A particle‐scale BEP initiation probabilistic model is first established based on fundamental grain kinetics under seepage flow by using the theory of rate processes. To investigate how soil variability influences initiation, a stochastic dual random lattice modeling framework is exercised, complemented by direct x‐ray computed tomography measurements of soil variability conducted on sand samples. The analytical probabilistic model for BEP initiation closely aligns with the Weibull distribution, also demonstrating that soil variability influences both the scale and shape parameters of the distribution. This work establishes the linkage between probability of BEP initiation as described by the theory of rate processes and phenomenological Weibull statistics. Findings presented herein bring the potential to develop a multiscale probabilistic framework by means of Weibull statistics for evaluating the probability of BEP initiation at multiple scales.
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Red-shifted activity-based sensors for ethylene via direct conjugation of fluorophore to metal–carbene
Direction conjugation of a BODIPY fluorophore with the chelating ruthenium ligand result in red-shifted ethylene probes Con-BEP-4 and Con-BEP-5. Synthesis, photophysical properties, and live cell imaging studies are reported.
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- Award ID(s):
- 1900482
- PAR ID:
- 10500728
- Publisher / Repository:
- Royal Society of Chemistry
- Date Published:
- Journal Name:
- RSC Chemical Biology
- Volume:
- 4
- Issue:
- 11
- ISSN:
- 2633-0679
- Page Range / eLocation ID:
- 871 to 878
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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