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Title: Tethering Three Radical Cascades for Controlled Termination of Radical Alkyne peri -Annulations: Making Phenalenyl Ketones without Oxidants
Award ID(s):
2102579
PAR ID:
10507168
Author(s) / Creator(s):
; ; ; ; ; ; ; ;
Publisher / Repository:
ACS
Date Published:
Journal Name:
Journal of the American Chemical Society
Volume:
146
Issue:
6
ISSN:
0002-7863
Page Range / eLocation ID:
4187 to 4211
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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    A multi-component radical addition strategy enables difunctionalization of alkenes with heteroarenes and a variety of radical precursors, including N 3 , P(O)R 2 , and CF 3 . This unified approach for coupling diverse classes of electrophilic radicals and heteroarenes to vinyl ethers allows for direct, vicinal C–C as well as C–N, C–P, and C–R f bond formation. 
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