skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Physical and biogeochemical drivers of solute mobilization and flux through the critical zone after wildfire
A nine-year time series of nutrient cation and anion concentration and efflux from three forested catchments in the Jemez River Basin Critical Zone Observatory (JRB-CZO) in northern New Mexico was used to quantify the pulse of chemical denudation resulting from varying levels stand-replacing wildfire intensity in May-June of 2013. The 3 years of pre-fire and 6 years of postfire data were also probed to shed light on the mechanisms underlying the pulsed release and the subsequent recovery. The initial large solute pulse released to the streams—K+, Ca2+, Mg2+, SO 4 2 - , Cl, dissolved inorganic carbon (DIC), dissolved organic carbon (DOC), and total dissolved nitrogen (TDN)—was caused by leaching of hillslope ash deposits during the first monsoon storms post-fire. Debris flow following the wildfire likely redistributed much of the ash-containing sediments along streams and valley bottoms. Sustained elevated solute concentrations observed in the surface waters throughout the post-fire period relative to pre-fire baselines is consistent with these soluble materials being periodically flushed from the soils during wet seasons, i.e., snowmelt and summer monsoons. As microbial mediated reactions and biotic uptake—due to plant regrowth—recover after fire, nutrient ion export (e.g., NO 3 - , Cland SO 4 2 - ) steadily decreased toward the end of the post fire period, but remained above pre-fire levels, particularly for NO 3 - and SO 4 2 - . Surface water concentrations of polyvalent cations (e.g., Al and Fe) decreased significantly after the fire. Our observations suggest that changes in organic matter composition after fire (e.g., increased humification index—HIX) and the presence of pyrogenic carbon may not favor organo-metal complexation and transport. Finally, differences in burn severity among the three watersheds presented in this study, provide insights of the relative impact of solute exports and resilience. The catchments that experienced high burn severity exhibited greater solute fluxes than the less severely burn. Moreover, despite these differences, toward the end of the post-fire period these surface waters presented low and similar solute effluxes, indicating system recovery. Nonetheless, magnitudes and rebounds were solute and process specific. The results of this study highlight the importance of surface and near surface physical and biogeochemical processes on the long-lasting geochemical denudation of forested catchments following wildfires of varying intensities.  more » « less
Award ID(s):
2012123
PAR ID:
10511199
Author(s) / Creator(s):
; ; ; ; ;
Publisher / Repository:
Frontiers
Date Published:
Journal Name:
Frontiers in Water
Volume:
5
ISSN:
2624-9375
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. The increasing severity and frequency of wildfires in forested watersheds pose significant challenges to water quality management. This study examines the impacts of the 2022 Hermit's Peak-Calf Canyon gigafire, the largest wildfire in New Mexico's history. The wildfire burned over 1,382 km2, affecting a key watershed that supplies drinking water to Las Vegas, NM. We conducted a longitudinal assessment of post-fire water quality dynamics across a 170 km fluvial network, analyzing flow, water quality parameters, nutrient and metal concentrations, and mobilization patterns. We found that post-fire nutrient concentrations exceeded pre-fire medians by up to two orders of magnitude. Our analyses revealed solute-specific transport patterns that are difficult to predict with static watershed- or fire-specific characteristics (e.g., burned area and percent severities). NH 4 + , PO 3 - , and NO 2 - were closely and positively associated with discharge and turbidity near the burn perimeter, while NO 3 - and TON exhibited strong mobilization trends ~170 km downstream. In contrast to nutrients, calcium, magnesium, and manganese levels showed no significant pre- vs. post-fire shifts, while concentrations of trace metals like Cr3+, Pb2+, Zn2+, and Sr2+surpassed background levels and public health thresholds. Our findings emphasize the significant propagation of wildfire disturbances over hundreds of kilometers and suggest the need for integrated watershed management strategies, including the management of large-scale flood control mechanisms to mitigate the far-reaching impacts of water quality disturbances post-fire. 
    more » « less
  2. Moreno, O (Ed.)
    An overview of neutron skin predictions obtained using an empirical nonlocal dispersive optical model (DOM) is presented. The DOM links both scattering and bound-state experimental data through a subtracted dispersion relation which allows for fully consistent, data-informed predictions for nuclei where such data exist. Large skins were predicted for both48Ca ( R skin 48 = 0.25 ± 0.023 fm in 2017) and208Pb ( R skin 208 = 0.25 ± 0.05 fm in 2020). Whereas the DOM prediction in208Pb is within 1 σ of the subsequent PREX-2 measurement, the DOM prediction in48Ca is over 2 σ larger than the thin neutron skin resulting from CREX. From the moment it was revealed, the thin skin in48Ca has puzzled the nuclear-physics community as no adequate theories simultaneously predict both a large skin in208Pb and a small skin in48Ca. The DOM is unique in its ability to treat both structure and reaction data on the same footing, providing a unique perspective on this R skin puzzle. It appears vital that more neutron data be measured in both the scattering and bound-state domain for48Ca to clarify the situation. 
    more » « less
  3. Abstract We extend the Calderón–Zygmund theory for nonlocal equations tostrongly coupled system of linear nonlocal equations A s u = f {\mathcal{L}^{s}_{A}u=f}, where the operator A s {\mathcal{L}^{s}_{A}}is formally given by A s u = n A ( x , y ) | x - y | n + 2 s ( x - y ) ( x - y ) | x - y | 2 ( u ( x ) - u ( y ) ) 𝑑 y . \mathcal{L}^{s}_{A}u=\int_{\mathbb{R}^{n}}\frac{A(x,y)}{|x-y|^{n+2s}}\frac{(x-%y)\otimes(x-y)}{|x-y|^{2}}(u(x)-u(y))\,dy. For 0 < s < 1 {0<1}and A : n × n {A:\mathbb{R}^{n}\times\mathbb{R}^{n}\to\mathbb{R}}taken to be symmetric and serving asa variable coefficient for the operator, the system under consideration is the fractional version of the classical Navier–Lamé linearized elasticity system. The study of the coupled system of nonlocal equations is motivated by its appearance in nonlocal mechanics, primarily in peridynamics. Our regularity result states that if A ( , y ) {A(\,\cdot\,,y)}is uniformly Holder continuous and inf x n A ( x , x ) > 0 {\inf_{x\in\mathbb{R}^{n}}A(x,x)>0}, then for f L loc p {f\in L^{p}_{\rm loc}}, for p 2 {p\geq 2}, the solution vector u H loc 2 s - δ , p {u\in H^{2s-\delta,p}_{\rm loc}}for some δ ( 0 , s ) {\delta\in(0,s)}. 
    more » « less
  4. Abstract The nucleus206Po was studied in the two proton transfer reaction204Pb(16O,14C)206Po and the lifetime of the first excited 2+state was determined by utilizing the Recoil Distance Doppler Shift method. The experimental results are compared with shell-model calculations based on different effective interactions. The calculations qualitatively reproduced the experimentally observed B ( E 2 ; 2 1 + 0 1 + ) value, suggesting that the 2 1 + state of206Po exhibits a collective nature. However, the employed effective interactions revealed some limitations, particularly in their description of the 4 1 , 2 + states. These results emphasize the importance of understanding the properties of low-lying states, especially their evolution from single-particle dynamics to collective modes, in evaluating various effective nuclear interactions. 
    more » « less
  5. Abstract We present Keck Planet Imager and Characterizer (KPIC) high-resolution (R∼35,000)K-band thermal emission spectroscopy of the ultrahot Jupiter WASP-33b. The use of KPIC’s single-mode fibers greatly improves both blaze and line-spread stabilities relative to slit spectrographs, enhancing the cross-correlation detection strength. We retrieve the dayside emission spectrum with a nested-sampling pipeline, which fits for orbital parameters, the atmospheric pressure–temperature profile, and the molecular abundances. We strongly detect the thermally inverted dayside and measure mass-mixing ratios for CO ( logCO MMR = 1.1 0.6 + 0.4 ), H2O ( logH 2 O MMR = 4.1 0.9 + 0.7 ), and OH ( logOH MMR = 2.1 1.1 + 0.5 ), suggesting near-complete dayside photodissociation of H2O. The retrieved abundances suggest a carbon- and possibly metal-enriched atmosphere, with a gas-phase C/O ratio of 0.8 0.2 + 0.1 , consistent with the accretion of high-metallicity gas near the CO2snow line and post-disk migration or with accretion between the soot and H2O snow lines. We also find tentative evidence for12CO/13CO ∼ 50, consistent with values expected in protoplanetary disks, as well as tentative evidence for a metal-enriched atmosphere (2–15 × solar). These observations demonstrate KPIC’s ability to characterize close-in planets and the utility of KPIC’s improved instrumental stability for cross-correlation techniques. 
    more » « less