skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.

Explore Research Products in the PAR
It may take a few hours for recently added research products to appear in PAR search results.


  • NSF Public Access
  • Search Results
  • Long-chain plant wax n-alkane hydrogen isotopic evidence for increased Little Ice Age aridity in the midcontinental United States
Title: Long-chain plant wax n-alkane hydrogen isotopic evidence for increased Little Ice Age aridity in the midcontinental United States
We compare hydrogen isotopic measurements of long-chain leaf-wax n-alkanes (2Hw; C27, C29, and C31) from Martin Lake, IN, United States of America (USA), with a calcite-based reconstruction of the oxygen isotopic composition of precipitation (18Op) from the same lake. We observe stable and high 2Hw during the Common Era (last 2000 years), which we interpret as growing-season precipitation originating mainly from the Gulf of Mexico and Atlantic. During the Little Ice Age (LIA; 1200-1850 CE), 2Hw values increased by 3-8 ‰, concomitant with a significant decrease in 18Op values by up to 12.5 ‰. Multiple proxy records for this time indicate persistent growing-season drought. We interpret these relatively high 2Hw values, as compared to the 18Op values, as a signal of low relative humidity that resulted in an 2H enrichment in plant source water resulting in high 2H values through enhanced plant water and/or soil evaporation. These results support the occurrence of low humidity conditions during the LIA in the midcontinental USA that also contributed to the marked decline of regional pre-Columbian Mississippian populations.  more » « less
Award ID(s):
1903628
PAR ID:
10511374
Author(s) / Creator(s):
; ;
Publisher / Repository:
Journal of Paleolimnology
Date Published:
Journal Name:
Journal of Paleolimnology
ISSN:
0921-2728
Subject(s) / Keyword(s):
Hydroclimate Paleoclimate Common Era Medieval Climate Anomaly Current Warm Period
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. ; (, Geochimica et Cosmochimica Acta)
    We analyzed the deuterium composition of individual plant-waxes in lake sediments from 28 watersheds that span a range of precipitation D/H, vegetation types and climates. The apparent isotopic fractionation (εa) between plant-wax n-alkanes and precipitation differs with watershed ecosystem type and structure, and decreases with increasing regional aridity as measured by enrichment of 2H and 18O associated with evaporation of lake waters. The most negative εa values represent signatures least affected by aridity; these values were −125 ± 5‰ for tropical evergreen and dry forests, −130‰ for a temperate broadleaf forest, −120 ± 9‰ for the high-altitude tropical páramo (herbs, shrubs and grasses), and −98 ± 6‰ for North American montane gymnosperm forests. Minimum εa values reflect ecosystem-dependent differences in leaf water enrichment and soil evaporation. Slopes of lipid/lake water isotopic enrichments differ slightly with ecosystem structure (i.e. open shrublands versus forests) and overall are quite small (slopes = 0–2), indicating low sensitivity of lipid δD variations to aridity compared with coexisting lake waters. This finding provides an approach for reconstructing ancient precipitation signatures based on plant-wax δD measurements and independent proxies for lake water changes with regional aridity. To illustrate this approach, we employ paired plant-wax δD and carbonate-δ18O measurements on lake sediments to estimate the isotopic composition of Miocene precipitation on the Tibetan plateau. 
    more » « less
  2. ; ; ; ; ; ; ; ; ; (, Hydrology and Earth System Sciences)
    Abstract. As global warming progresses, changes in high-latitude precipitation are expected to impart long-lasting impacts on Earth systems, including glacier mass balance and ecosystem structures. Reconstructing past changes in high-latitude precipitation and hydroclimate from networks of continuous lake records offers one way to improve forecasts of precipitation and precipitation–evaporation balances, but these reconstructions are currently hindered by the incomplete understanding of controls on lake and soil water isotopes. Here, we study the distribution of modern water isotopes in Icelandic lakes, streams, and surface soils collected in 2002, 2003, 2004, 2014, 2019, and 2020 to understand the geographic, geomorphic, and environmental controls on their regional and interannual variability. We find that lake water isotopes in open-basin (through-flowing) lakes reflect local precipitation, with biases toward the cold season, particularly in lakes with sub-annual residence times. Closed-basin lakes have water isotope and deuterium excess values consistent with evaporative enrichment. Interannual and seasonal variabilities of lake water isotopes at repeatedly sampled sites are consistent with instrumental records of winter snowfall; summer relative humidity; and atmospheric circulation patterns, such as the North Atlantic Oscillation. Summer surface soil water isotopes span the entire range of seasonal precipitation values in Iceland and appear to be consistently overprinted by evaporative enrichment, which can occur throughout the year, although the sampling depths were shallower than rooting depths for many plant types. This dataset provides new insight into the functionality of water isotopes in Icelandic environments and offers renewed possibilities for optimized site selection and proxy interpretation in future paleohydrological studies on this North Atlantic outpost. 
    more » « less
  3. ; ; ; ; ; ; ; ; ; ; et al (, Geologic Society of America)
    Recent studies have improved our understanding of how karst hydrology impacts variability in modern cave drip water δ18O values and the resultant calcite δ18O values of speleothem paleoclimate records. Monitoring of cave drip water isotope values reveals that flow path controls the differences in drip site values in many caves worldwide. We present a case study of three caves from the central Peruvian Andes where isotopic differences between sites are informed by monitoring data. Relative humidity at Huagapo and Pacupahuain caves is 100% year-round with no fluctuations, so any isotopic fractionation of waters must occur in the vadose zone or epikarst. Precipitation isotope data from the 2022-2023 year show differences with elevation, where annual mean precipitation at 3600 masl (meters above sea level) is, on average, 2‰ greater than precipitation at 4100 masl. Cave drip water was sampled four times (April, June, and November 2022, and June 2023). Average drip water δ18O values were lowest at the high elevation (4004 masl) cave of Antipayargunan -14.7 ± 2.5‰; similar values were found at the lowest elevation (3600 masl) cave of Huagapo -14.5 ± 1.2‰. Pacupahuain cave had the highest values with an average of -13.9 ± 1.7‰. The higher values at Pacupahuain Cave (3800 masl) may be attributed to higher evaporation due to vadose zone residence time, a lower average recharge elevation for this catchment and/or potential contribution from a sinkhole lake (Lago Gallerina) above the cave. Huagapo Cave is large, and sampling sites over 1 km in distance show that the δ18O value of drip water increases by 0.5‰ with increasing distance from the cave entrance. Drip counting sensor data and a continuous SYP autosampler at Pacupahuain Cave provide a time series showing that drip rate peaks during the monsoon season. More specifically, the data show a maximum of 2 ‰ difference in drip water at the autosampler site between the end of the wet season in May and the middle of the dry season in August – at which point drips cease for six months. Seasonal recharge dominates most drip water sites, while drip counters show evidence for fracture and diffuse flow-dominated drip sites. These data suggest that, similar to other cave sites, flow path is important for intra-cave differences in drip water isotope values. However, we find that karst hydrology plays a more dominant role between caves. 
    more » « less
  4. ; ; ; (, Paleoceanography and Paleoclimatology)
    Abstract Arctic precipitation is predicted to increase this century. Records of past precipitation seasonality provide baselines for a mechanistic understanding of the dynamics controlling Arctic precipitation. We present an approach to reconstruct Arctic precipitation seasonality using stable hydrogen isotopes (δ2H) of aquatic plant waxes in neighboring lakes with contrasting water residence times and present a case study of this approach in two lakes on western Greenland. Residence time calculations suggest that growing season lake water δ2H in one lake reflects summer precipitation δ2H, while the other reflects amount‐weighted annual precipitation δ2H and evaporative enrichment. Aquatic plant wax δ2H in the “summer lake” is relatively constant throughout the Holocene, perhaps reflecting competing effects of local summer warmth and increased distal moisture transport due to a strengthened latitudinal temperature gradient. In contrast, aquatic plant wax δ2H in the “mean annual lake” is 100‰2H depleted from 6 to 4 ka relative to the beginning and end of the record. Because there are relatively minor changes in summer precipitation δ2H, we interpret the 100‰2H depletion in mean annual precipitation to reflect an increase in winter precipitation amount, likely accompanied by changes in winter precipitation δ2H and decreased evaporative enrichment. Thus, unlike the “summer lake,” the “mean annual lake” records changes in winter precipitation. This dual‐lake approach may be applied to reconstruct past changes in precipitation seasonality at sites with strong precipitation isotope seasonality and minimal lake water evaporative enrichment. 
    more » « less
  5. ; ; ; ; ; ; ; (, NSF Arctic Data Center)
    This dataset contains the raw data associated with the manuscript entitled: Aquatic Moss δ18O as a Proxy for Seasonally Resolved Lake Water δ18O, Northwest Greenland (Puleo et al., 2024). Reconstructing past climate seasonality is fundamental to understanding the nature of past climate changes. This is especially true in the Arctic, where climate is intensely seasonal and proxies that can distinguish climate conditions of multiple seasons in a single year are relatively rare. We propose that submerged aquatic mosses, which are abundant subfossils in some Arctic lake sediments and have distinctive seasonal growth morphologies, can be used to estimate past lake water oxygen isotope composition (δ18Olw) across multiple seasons. Aquatic mosses are abundant, well preserved, and grow continuously in Arctic lakes whenever light is available, with some species displaying unique seasonal morphologies influenced by water temperature. Although Greenland paleorecords support that aquatic moss oxygen isotope values (δ18Oom) reflect the δ18O values of lake water, no modern calibration between δ18Oom and δ18Olw exists in Greenland, as aquatic moss samples are composed largely, but not entirely, of cellulose. We present a modern δ18Oom vs. δ18Olw calibration using multiple moss species or morphotypes from eight lakes and ponds near Pituffik (Thule), northwest Greenland. We find strong linear relationships between the δ18Oom and δ18Olw values of multiple species or morphotypes across the range of relatively low δ18Olw values at Pituffik, and our results indicate isotopic fractionations are similar to those found previously at lower latitudes. To assess the potential of mosses as archives of seasonal δ18Olw values, we analyzed δ18Oom in season-specific segments of moss strands, with seasons identified based upon growth morphology. Moss inferred lake water δ18O values (δ18Olwom) are higher in autumn than spring or summer, likely due to increasing contributions of isotopically heavier precipitation and the cumulative effects of lake water evaporation throughout the ice-free season. For moss subsampled throughout summer, δ18Olwom values generally increased through the season in parallel with observed δ18Olw values. Potential temperature dependent fractionation effects during biosynthesis, however, remain unconstrained and should be further addressed with future research. Overall, these findings suggest that aquatic mosses from lake sediments could be used to directly resolve climate seasonality of the past. Puleo, P.J.K., Akers, P.D., Kopec, B.G., Welker, J.M., Bailey, H., Osburn, M.R., Riis, T., Axford, Y., 2024. Aquatic moss δ18O as a proxy for seasonally resolved lake water δ18O, northwest Greenland. Quaternary Science Reviews 334, 1-11. 
    more » « less
  • Citation Formats
  • MLA
  • APA
  • Chicago
  • BibTeX
  • Save / Share this Record
  • Send to Email