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Title: Advancing Pore‐Space‐Partitioned Metal–Organic Frameworks with Isoreticular Cluster Concept
Abstract Trigonal planar M3(O/OH) trimers are among the most important clusters in inorganic chemistry and are the foundational features of multiple high‐impact MOF platforms. Here we introduce a concept called isoreticular cluster series and demonstrate that M3(O/OH), as the first member of a supertrimer series, can be combined with a higher hierarchical member (double‐deck trimer here) to advance isoreticular chemistry. We report here an isoreticular series of pore‐space‐partitioned MOFs called M3M6pacsmade from co‐assembly between M3single‐deck trimer and M3x2double‐deck trimer. Important factors were identified on this multi‐modular MOF platform to guide optimization of each module, which enables the phase selection of M3M6pacsby overcoming the formation of previously‐always‐observed same‐cluster phases. The newpacsmaterials exhibit high surface area and high uptake capacity for CO2and small hydrocarbons, as well as selective adsorption properties relevant to separation of industrially important mixtures such as C2H2/CO2and C2H2/C2H4. Furthermore, new M3M6pacsmaterials show electrocatalytic properties with high activity.  more » « less
Award ID(s):
2154375
PAR ID:
10515203
Author(s) / Creator(s):
; ; ; ;
Publisher / Repository:
Wiley
Date Published:
Journal Name:
Angewandte Chemie International Edition
ISSN:
1433-7851
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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