skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Investigating a new approach for magnetic ionic liquids: Dispersive liquid-liquid microextraction coupled to pyrolysis gas-chromatography-mass spectrometry to determine flame retardants in sewage sludge samples
Award ID(s):
2203891
PAR ID:
10523349
Author(s) / Creator(s):
; ; ; ; ; ;
Publisher / Repository:
Elsevier
Date Published:
Journal Name:
Journal of Chromatography A
Volume:
1730
Issue:
C
ISSN:
0021-9673
Page Range / eLocation ID:
465038
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Zhou, Huan-Xiang (Ed.)
    Liquid condensate droplets with distinct compositions of proteins and nucleic acids are widespread in biological cells. While it is known that such droplets, or compartments, can regulate irreversible protein aggregation, their effect on reversible self-assembly remains largely unexplored. In this article, we use kinetic theory and solution thermodynamics to investigate the effect of liquid-liquid phase separation on the reversible self-assembly of structures with well-defined sizes and architectures. We find that, when assembling subunits preferentially partition into liquid compartments, robustness against kinetic traps and maximum achievable assembly rates can be significantly increased. In particular, both the range of solution conditions leading to productive assembly and the corresponding assembly rates can increase by orders of magnitude. We analyze the rate equation predictions using simple scaling estimates to identify effects of liquid-liquid phase separation as a function of relevant control parameters. These results may elucidate self-assembly processes that underlie normal cellular functions or pathogenesis, and suggest strategies for designing efficient bottom-up assembly for nanomaterials applications. 
    more » « less
  2. null (Ed.)
  3. Liquid metals such as gallium alloys have a unique potential to enable fully reconfigurable RF electronics. One of the major concerns for liquid-metal electronics is their interaction with solid-metal contacts, which results in unwanted changes to electrical performance and delamination of solid-metal contacts due to atomic diffusion of gallium at the liquid/solid interface. In this paper, we present a solution to this problem through way of liquid-metal/liquid-metal RF connections by implementing Laplace barriers, which control fluid flow and position via pressure-sensitive thresholds to facilitate physical movement of the fluids within the channels. We demonstrate RF switching within the channel systems by fabricating, testing, and modeling a reconfigurable RF microstrip transmission line with integrated Laplace barriers which operates between 0.5–5 GHz. This approach opens the potential for future all-liquid reconfigurable RF electronic circuits where physical connections between solid and liquid metals are minimized or possibly eliminated altogether. 
    more » « less