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Sub-nanoliter volumes of the Belousov-Zhabotinsky (BZ) reaction are sealed in microfluidic devices made from polydimethylsiloxane (PDMS). Bromine, which is a BZ reaction intermediate that participates in the inhibitory pathway of the reaction, is known to permeate into PDMS, and it has been suggested that PDMS and bromine can react ( J. Phys. Chem. A. 108, 2004, 1325-1332). We characterize the extent to which PDMS affects BZ oscillations by varying the volume of the PDMS surrounding the BZ reactors. We measure how the oscillation period varies with PDMS volume and compare with a theoretical reaction-diffusion model, concluding that bromine reacts with PDMS. We demonstrate that minimizing the amount of PDMS by making the samples as thin as possible maximizes the number of oscillations before the BZ reaction reaches equilibrium and ceases to oscillate. We also demonstrate that the deleterious effects of the PDMS-BZ interactions are somewhat mitigated by imposing constant chemical boundary conditions through using a light-sensitive catalyst, ruthenium, in combination with patterned illumination. Furthermore, we show that light can modulate the frequency and phase of the BZ oscillators contained in a PDMS matrix by 20-30%.
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Chemistry does general relativity: reaction-diffusion waves can model gravitational lensing
Gravitational lensing is a general relativistic (GR) phenomenon where a massive object redirects light, deflecting, magnifying, and sometimes multiplying its source. We use reaction-diffusion (RD) Belousov-Zhabotinsky (BZ) chemistry to study this astronomical effect in a table-top experiment. We experimentally observe BZ waves passing through non-planar, quasi-two-dimensional molds and reproduce the waveforms in computer simulations using planar RD waves propagating with variable diffusion. We tune the variable diffusion to match the Schwarzschild-coordinate light speed near a spherical mass so the RD propagation approximates Einstein’s famous light deflection relation. We discuss varying the diffusion or reaction rates with a gel matrix or with illumination, electric field, or temperature gradients.
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- Award ID(s):
- 1852095
- PAR ID:
- 10524134
- Publisher / Repository:
- Frontiers
- Date Published:
- Journal Name:
- Frontiers in Physics
- Volume:
- 11
- ISSN:
- 2296-424X
- Subject(s) / Keyword(s):
- Belousov-Zhabotinsky reaction gravitational lensing reaction-diffusion waves general relativity, Barkley model astrophysical analogs
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.3389/fphy.2023.1315966
