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Understanding of climate parameters and hydrology during past greenhouse conditions is important to forecasting future climate conditions. Oxygen isotopes of vertebrate bioapatites offer an opportunity to sample conditions across ancient landscapes. 112 samples from a variety of ecological niches were sampled from Cloverly Formation (Lower Cretaceous) micro-vertebrate site V1075 reposited at the Sam Nobel Museum at the University of Oklahoma. These samples were analyzed at the Keck Paleoenvironmental and Environmental Stable Isotope lab at the University of Kansas. Phosphate δ18O values range from between 9‰ to 23‰ vs. SMOW and show significant variability based on interpreted ecological niche of the taxa. Utilizing crocodilian and turtle d18Op values, environmental water oxygen isotope values are interpreted to be approximately -8‰ SMOW. These values are about 2-4‰ enriched relative to past estimates based on latitudinal gradients from penecontemporaneous formations from other latitudes. Based on water isotope estimates, fish δ18O values were used to calculate water temperature values of ~26°C which is consistent with estimated temperatures based on latitudinal gradients for the Cretaceous. In addition, preliminary carbonate clumped isotope paleothermometry suggest similar temperatures. These results along with emerging data from similar age deposits are beginning to build an emerging view of climate on the western side of the Western Interior Seaway during the late Early Cretaceous.
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Reconstructing paleoenvironments of the Late Cretaceous Western Interior Seaway, USA, using paired triple oxygen and carbonate clumped isotope measurements
Fossiliferous carbonate concretions are commonly found in sediments deposited in the Late Cretaceous Western Interior Seaway. Although concretions are diagenetic features, well-preserved fossils from within them have been instrumental in reconstructing the temperature and δ18O value of Western Interior Seaway seawater, which is essential for accurate reconstruction of Late Cretaceous climate. Here, we constrain formation conditions of Late Campanian and early Maastrichtian carbonate concretions by combining triple oxygen isotope measurements with carbonate clumped isotope paleothermometry on different carbonate phases within the concretions. We measured both fossil skeletal aragonite and sparry calcite infill from cracks and within macrofossil voids to evaluate differences between “primary” and “altered” geochemical signals. Based on the two temperature-sensitive isotope systems of the primary fossil shell aragonite, the temperature of the Western Interior Seaway was between 20 °C and 40 °C and was likely thermally stratified during the Campanian. The reconstructed δ18Oseawater values of ∼−1‰ for Campanian Western Interior Seaway waters are similar to those expected for the open ocean during greenhouse climates, while the Maastrichtian Western Interior Seaway may have been more restricted, with a δ18Oseawater value of ∼2‰, which reflects more evaporative conditions. We reconstructed the diagenetic history of the sparry infill and altered fossils using a fluid-rock mixing model. Alteration temperature, alteration fluid δ18O value, and the initial formation temperature were calculated by applying the fluid-rock mixing model to a particle swarm optimization algorithm. We found a different range of initial formation temperatures between the Campanian (25−38 °C) and Maastrichtian (9−28 °C). We also found that alteration in the presence of light meteoric fluids (δ18O ≈ −10‰) is required to explain both the sparry infill and the altered fossil isotopic values. Based on our results, both lithification and alteration of the carbonates occurred soon after burial, and light meteoric fluids support prior findings that high-topographic relief existed on the western margin of the Western Interior Seaway during the Late Cretaceous. As one of the first studies to apply these techniques in concert and across multiple mineralogical phases within samples, our results provide important constraints on paleoenvironmental conditions in an enigmatic ocean system and will improve interpretations of the overall health of ecosystems leading into the end-Cretaceous mass extinction.
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- Award ID(s):
- 1952615
- PAR ID:
- 10528730
- Publisher / Repository:
- Geological Society of America Bulletin
- Date Published:
- Journal Name:
- Geological Society of America Bulletin
- ISSN:
- 0016-7606
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1130/B37543.1
