skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Untangling the chemical complexity of plastics to improve life cycle outcomes
A diversity of chemicals are intentionally added to plastics to enhance their properties and aid in manufacture. Yet, the accumulated chemical composition of these materials is essentially unknown even to those within the supply chain, let alone to consumers or recyclers. Recent legislated and voluntary commitments to increase recycled content in plastic products highlight the practical challenges wrought by these chemical mixtures, amid growing public concern about the impacts of plastic-associated chemicals on environmental and human health. In this Perspective, we offer guidance for plastics manufacturers to collaborate across sectors and critically assess their use of added chemicals. The ultimate goal is to use fewer and better additives to promote a circular plastics economy with minimal risk to humans and the environment.  more » « less
Award ID(s):
1840381 2418297
PAR ID:
10532785
Author(s) / Creator(s):
; ; ;
Publisher / Repository:
PMC
Date Published:
Journal Name:
Nature Reviews Materials
ISSN:
2058-8437
Subject(s) / Keyword(s):
plastics microplastics recycling manufacturing hazard assessment
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Plastics recycling is an important component of the circular economy. In mechanical recycling, the recovery of high-quality plastics for subsequent reprocessing requires plastic waste to be first sorted by type, color, and size. In chemical recycling, certain types of plastics should be removed first as they negatively affect the process. Such sortation of plastic objects at Materials Recovery Facilities (MRFs) relies increasingly on automated technology. Critical for any sorting is the proper identification of the plastic type. Spectroscopy is used to this end, increasingly augmented by machine learning (ML) and artificial intelligence (AI). Recent developments in the application of ML/AI in plastics recycling are highlighted here, and the state of the art in the identification and sortation of plastic is presented. Commercial equipment for sorting plastic recyclables is identified from a survey of publicly available information. Automated sorting equipment, ML/AI-based sorters, and robotic sorters currently available on the market are evaluated regarding their sensors, capability to sort certain types of plastics, primary application, throughput, and accuracy. This information reflects the rapid progress achieved in sorting plastics. However, the sortation of film, dark plastics, and plastics comprising multiple types of polymers remains challenging. Improvements and/or new solutions in the automated sorting of plastics are forthcoming. 
    more » « less
  2. Abstract Researchers have made headway against challenges of increasing cement infrastructure and low plastic recycling rates by using waste plastic in cementitious materials. Past studies indicate that microbially induced calcium carbonate precipitation (MICP) to coat plastic in calcium carbonate may improve the strength. The objective of this study was to increase the amount of clean and contaminated waste plastic that can be added to mortar and to assess whether MICP treatment enhances the strength. The performance of plastic-filled mortar was investigated at 5%, 10%, and 20% volume replacement for cement. Untreated, clean plastics at a 20% cement replacement produced compressive strengths acceptable for several applications. However, a coating of MICP on clean waste plastic did not improve the strengths. At 10% replacement, both MICP treatment and washing of contaminated plastics recovered compressive strengths by approximately 28%, relative to mortar containing oil-coated plastics. By incorporating greater volumes of waste plastics into mortar, the sustainability of cementitious composites has the potential of being improved by the dual mechanisms of reduced cement production and repurposing plastic waste. 
    more » « less
  3. One application of plastics that grew during the COVID-19 pandemic is for social distancing plastic shields, or protective barriers, made from polymethyl methacrylate (PMMA) such as transparent face guards. Although available for other applications, end-of-life impacts for barriers are currently lacking in the literature, and there is a need to fill in this gap to guide decisions. This study evaluated the end-of-life environmental impacts of PMMA barriers in the United States by using life cycle assessment. We evaluated five strategies including landfilling, waste-to-energy, mechanical recycling, chemical recycling and reuse. Data were sourced from literature and various life cycle inventory databases. The Tool for Reduction and Assessment of Chemicals and Other Environmental Impacts (TRACI) was used as the life cycle impact assessment method. Landfilling exhibited the highest impact in all indicators and reuse demonstrated optimal results for global warming potential. A scenario analysis was conducted to explore a combination of strategies, revealing that the most promising approach involved a mix of 40% reuse, 20% mechanical recycling and 40% chemical recycling. Circular economy recommendations are proposed for managing these sources of plastic waste in the United States. 
    more » « less
  4. Abstract Various chemical transformation approaches are being actively developed to address the environmental accumulation of plastic waste. However, most postconsumer plastics are heterogeneous, exhibit high melt viscosity, and are insoluble in most conventional solvents. Such properties result in transport‐limiting chemical transformations, low conversion rates, and low product selectivity. Although supercritical fluids (SCFs) have been a matter of continuing scientific interest in several mass‐transfer processes, the use of SCFs as tunable media for the chemical transformation of postconsumer plastics is still in its early stages, but has rapidly advanced in recent years. Therefore, this review reports on the current state‐of‐art of chemical transformation of plastics using SCFs. It addresses the effects of sub and supercritical CO2(scCO2) on solvolysis‐based technologies. Additionally, it reviews recent advances on the use of supercritical organic solvents (e.g., ethanol, methanol) and supercritical water (SCW) as reaction media for the solvolysis and liquefaction of plastics, respectively, and the latest developments in the simultaneous conversion of CO2and waste plastics. Overall, developing technologies that minimize mass transfer limitations during the chemical transformation of plastics is critical to overcoming some of the major bottlenecks hampering product yield and selectively, and ultimately the economic viability of plastics recycling and upcycling. 
    more » « less
  5. Abstract The global production and consumption of plastics has increased at an alarming rate over the last few decades. The accumulation of pervasive and persistent waste plastic has concomitantly increased in landfills and the environment. The societal, ecological, and economic problems of plastic waste/pollution demand immediate and decisive action. In 2015, only 9% of plastic waste was successfully recycled in the United States. The major current recycling processes focus on the mechanical recycling of plastic waste; however, even this process is limited by the sorting/pretreatment of plastic waste and degradation of plastics during the process. An alternative to mechanical processes is chemical recycling of plastic waste. Efficient chemical recycling would allow for the production of feedstocks for various uses including fuels and chemical feedstocks to replace petrochemicals. This review focuses on the most recent advances for the chemical recycling of three major polymers found in plastic waste: PET, PE, and PP. Commercial processes for recycling hydrolysable polymers like polyesters or polyamides, polyolefins, or mixed waste streams are also discussed. 
    more » « less