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1. Electrodeposition of Ru onto Ru and Au Seed Layers from Solutions of Ruthenium Nitrosyl Sulfate and Ruthenium Chloride

   https://doi.org/10.1149/1945-7111/abff68  

   Gusley, Ryan; Cumston, Quintin; Coffey, Kevin R.; West, Alan C.; Barmak, Katayun (May 2021, Journal of The Electrochemical Society)

   The electrodeposition of Ru was investigated from solutions of ruthenium(III) nitrosyl sulfate and ruthenium(III) chloride onto seed layers of epitaxial and polycrystalline Ru and epitaxial Au. Using both galvanostatic and potentiostatic deposition modes, metallic Ru was found to electrodeposit as a porous layer comprised of (0001) oriented Ru crystallites, the presence of which was discovered and confirmed by X-ray and scanning transmission and transmission electron microscope (S/TEM) analyses. This finding was independent of the Ru salt and seed layer used. Using X-ray reflectivity (XRR), the average film density ${\rho }_{eff}$of the porous electrodeposited Ru layer was measured as less than the density of bulk Ru ${\rho }_{Ru,bulk}$(14.414 g cm⁻³). Increasing the magnitude of the applied current density from −100μA cm⁻²to −10 mA cm⁻²in solutions of Ru nitrosyl sulfate increased the ${\rho }_{eff}$from 7.4 g cm⁻³to 9.7 g cm⁻²while the current efficiency decreased from 9.4% to 4.3%. 

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2. Planck Dust Polarization Power Spectra Are Consistent with Strongly Supersonic Turbulence

   https://doi.org/10.3847/1538-4357/ad571b  

   Stalpes, Kye_A; Collins, David_C; Huffenberger, Kevin_M (August 2024, The Astrophysical Journal)

   Abstract The polarization of the cosmic microwave background is rich in information but obscured by foreground emission from the Milky Way’s interstellar medium (ISM). To uncover relationships between the underlying turbulent ISM and the foreground power spectra, we simulated a suite of driven, magnetized, turbulent models of the ISM, varying the fluid properties via the sonic Mach number, ${\mathcal{M}}_{\mathcal{S}}$, and magnetic (Alfvén) Mach number, ${\mathcal{M}}_{\mathrm{A}}$. We measure the power spectra of density (ρ), velocity (v), magnetic field (H), total projected intensity (T), parity-even polarization (E), and parity-odd polarization (B). We find that the slopes of all six quantities increase with ${\mathcal{M}}_{\mathcal{S}}$. Most increase with ${\mathcal{M}}_{\mathrm{A}}$, while the magnetic field spectrum steepens with ${\mathcal{M}}_{\mathrm{A}}$. By comparing spectral slopes ofEandBto those measured by Planck, we infer typical values of ${\mathcal{M}}_{\mathcal{S}}$and ${\mathcal{M}}_{\mathrm{A}}$for the ISM. As the fluid velocity increases, ${\mathcal{M}}_{\mathcal{S}}>4$, the ratio of BB power to EE power increases to approach a constant value near the Planck-observed value of ∼0.5, regardless of the magnetic field strength. We also examine correlation coefficients between projected quantities, and find thatr^TE≈ 0.3, in agreement with Planck, for appropriate combinations of ${\mathcal{M}}_{\mathcal{S}}$and ${\mathcal{M}}_{\mathrm{A}}$. Finally, we consider parity-violating correlationsr^TBandr^EB. 

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3. Validation of Elemental and Isotopic Abundances in Late-M Spectral Types with the Benchmark HIP 55507 AB System

   https://doi.org/10.3847/1538-4357/ad1243  

   Xuan, Jerry W.; Wang, Jason; Finnerty, Luke; Horstman, Katelyn; Grimm, Simon; Peck, Anne E.; Nielsen, Eric; Knutson, Heather A.; Mawet, Dimitri; Isaacson, Howard; et al (February 2024, The Astrophysical Journal)

   Abstract M dwarfs are common host stars to exoplanets but often lack atmospheric abundance measurements. Late-M dwarfs are also good analogs to the youngest substellar companions, which share similarT_eff∼ 2300–2800 K. We present atmospheric analyses for the M7.5 companion HIP 55507 B and its K6V primary star with Keck/KPIC high-resolution (R∼ 35,000)K-band spectroscopy. First, by including KPIC relative radial velocities between the primary and secondary in the orbit fit, we improve the dynamical mass precision by 60% and find $M_B={88.0}_{-3.2}^{+3.4}{M}_{\mathrm{Jup}}$, putting HIP 55507 B above the stellar–substellar boundary. We also find that HIP 55507 B orbits its K6V primary star with $a={38}_{-3}^{+4}$au ande= 0.40 ± 0.04. From atmospheric retrievals of HIP 55507 B, we measure [C/H] = 0.24 ± 0.13, [O/H] = 0.15 ± 0.13, and C/O = 0.67 ± 0.04. Moreover, we strongly detect¹³CO (7.8σsignificance) and tentatively detect ${\mathrm{H}}_2^{18}\mathrm{O}$(3.7σsignificance) in the companion’s atmosphere and measure ${}^{12}\mathrm{CO}{/}^{13}\mathrm{CO}={98}_{-22}^{+28}$and ${\mathrm{H}}_2^{16}\mathrm{O}/{\mathrm{H}}_2^{18}\mathrm{O}={240}_{-80}^{+145}$after accounting for systematic errors. From a simplified retrieval analysis of HIP 55507 A, we measure ${}^{12}\mathrm{CO}{/}^{13}\mathrm{CO}={79}_{-16}^{+21}$and ${\mathrm{C}}^{16}\mathrm{O}/{\mathrm{C}}^{18}\mathrm{O}={288}_{-70}^{+125}$for the primary star. These results demonstrate that HIP 55507 A and B have consistent¹²C/¹³C and¹⁶O/¹⁸O to the <1σlevel, as expected for a chemically homogeneous binary system. Given the similar flux ratios and separations between HIP 55507 AB and systems with young substellar companions, our results open the door to systematically measuring¹³CO and ${\mathrm{H}}_2^{18}\mathrm{O}$abundances in the atmospheres of substellar or even planetary-mass companions with similar spectral types. 

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4. The EDGE-CALIFA Survey: Spatially Resolved ¹³ CO(1–0) Observations and Variations in ¹² CO(1–0)/ ¹³ CO(1–0) in Nearby Galaxies on Kiloparsec Scales

   https://doi.org/10.3847/1538-4365/acd840  

   Cao, Yixian; Wong, Tony; Bolatto, Alberto D.; Leroy, Adam K.; Rosolowsky, Erik; Utomo, Dyas; Sánchez, Sebastián F.; Barrera-Ballesteros, Jorge K.; Levy, Rebecca C.; Colombo, Dario; et al (August 2023, The Astrophysical Journal Supplement Series)

   Abstract We present¹³CO(J= 1 → 0) observations for the EDGE-CALIFA survey, which is a mapping survey of 126 nearby galaxies at a typical spatial resolution of 1.5 kpc. Using detected¹²CO emission as a prior, we detect¹³CO in 41 galaxies via integrated line flux over the entire galaxy and in 30 galaxies via integrated line intensity in resolved synthesized beams. Incorporating our CO observations and optical IFU spectroscopy, we perform a systematic comparison between the line ratio ${\mathit{}}_{12/13}\equiv I{[}^{12}\mathrm{CO}(J=1\to 0)\left]/I{[}^{13}\mathrm{CO}\right(J=1\to 0\left)\right]$and the properties of the stars and ionized gas. Higher ${\mathit{}}_{12/13}$values are found in interacting galaxies compared to those in noninteracting galaxies. The global ${\mathit{}}_{12/13}$slightly increases with infrared colorF₆₀/F₁₀₀but appears insensitive to other host-galaxy properties such as morphology, stellar mass, or galaxy size. We also present azimuthally averaged ${\mathit{}}_{12/13}$profiles for our sample up to a galactocentric radius of 0.4r₂₅(∼6 kpc), taking into account the¹³CO nondetections by spectral stacking. The radial profiles of ${\mathit{}}_{12/13}$are quite flat across our sample. Within galactocentric distances of 0.2r₂₅, the azimuthally averaged ${\mathit{}}_{12/13}$increases with the star formation rate. However, Spearman rank correlation tests show the azimuthally averaged ${\mathit{}}_{12/13}$does not strongly correlate with any other gas or stellar properties in general, especially beyond 0.2r₂₅from the galaxy centers. Our findings suggest that in the complex environments in galaxy disks, ${\mathit{}}_{12/13}$is not a sensitive tracer for ISM properties. Dynamical disturbances, like galaxy interactions or the presence of a bar, also have an overall impact on ${\mathit{}}_{12/13}$, which further complicates the interpretations of ${\mathit{}}_{12/13}$variations. 

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5. No-boundary state for Klein space

   https://doi.org/10.1088/1751-8121/adc882  

   Melton, Walker; Sharma, Atul; Strominger, Andrew; Wang, Tianli (April 2025, Journal of Physics A: Mathematical and Theoretical)

   Abstract Analytic continuation from (3, 1) signature Minkowski to (2, 2) signature Klein space has emerged as a useful tool for the understanding of scattering amplitudes and flat space holography. Under this continuation, past and future null infinity merge into a single boundary ( $J$) which is the product of a null line with a (1, 1) signature torus. The Minkowskian $S$-matrix continues to a Kleinian $S$-vector which in turn may be represented by a Poincaré-invariant vacuum state $|C⟩$in the Hilbert space built on $J$. $|C⟩$contains all information about $S$in a novel, repackaged form. We give an explicit construction of $|C⟩$in a Lorentz/conformal basis for a free massless scalar. $J$separates into two halves $J_{\pm }$which are the asymptotic null boundaries of the regions timelike and spacelike separated from the origin. $|C⟩$is shown to be a maximally entangled state in the product of the $J_{\pm }$Hilbert spaces. 

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