skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Additive manufacturing of an ultrastrong, deformable Al alloy with nanoscale intermetallics
Abstract Light-weight, high-strength, aluminum (Al) alloys have widespread industrial applications. However, most commercially available high-strength Al alloys, like AA 7075, are not suitable for additive manufacturing due to their high susceptibility to solidification cracking. In this work, a custom Al alloy Al92Ti2Fe2Co2Ni2is fabricated by selective laser melting. Heterogeneous nanoscale medium-entropy intermetallic lamella form in the as-printed Al alloy. Macroscale compression tests reveal a combination of high strength, over 700 MPa, and prominent plastic deformability. Micropillar compression tests display significant back stress in all regions, and certain regions have flow stresses exceeding 900 MPa. Post-deformation analyses reveal that, in addition to abundant dislocation activities in Al matrix, complex dislocation structures and stacking faults form in monoclinic Al9Co2type brittle intermetallics. This study shows that proper introduction of heterogeneous microstructures and nanoscale medium entropy intermetallics offer an alternative solution to the design of ultrastrong, deformable Al alloys via additive manufacturing.  more » « less
Award ID(s):
2210152
PAR ID:
10541313
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ;
Publisher / Repository:
Nature
Date Published:
Journal Name:
Nature Communications
Volume:
15
Issue:
1
ISSN:
2041-1723
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. NA (Ed.)
    Abstract Multiprincipal-element alloys are an enabling class of materials owing to their impressive mechanical and oxidation-resistant properties, especially in extreme environments1,2. Here we develop a new oxide-dispersion-strengthened NiCoCr-based alloy using a model-driven alloy design approach and laser-based additive manufacturing. This oxide-dispersion-strengthened alloy, called GRX-810, uses laser powder bed fusion to disperse nanoscale Y2O3particles throughout the microstructure without the use of resource-intensive processing steps such as mechanical or in situ alloying3,4. We show the successful incorporation and dispersion of nanoscale oxides throughout the GRX-810 build volume via high-resolution characterization of its microstructure. The mechanical results of GRX-810 show a twofold improvement in strength, over 1,000-fold better creep performance and twofold improvement in oxidation resistance compared with the traditional polycrystalline wrought Ni-based alloys used extensively in additive manufacturing at 1,093 °C5,6. The success of this alloy highlights how model-driven alloy designs can provide superior compositions using far fewer resources compared with the ‘trial-and-error’ methods of the past. These results showcase how future alloy development that leverages dispersion strengthening combined with additive manufacturing processing can accelerate the discovery of revolutionary materials. 
    more » « less
  2. The empirical parameters of mixing enthalpy (ΔHmix), mixing entropy (ΔSmix), atomic radius difference (δ), valence electron concentration (VEC), etc., are used in this study to design a depleted uranium high-entropy alloy (HEA). X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) were used to assess the phase composition. Compression and hardness tests were conducted to select alloy constituents with outstanding mechanical properties. Based on the experimental results, the empirical criteria of HEAs are an effective means to develop depleted uranium high-entropy alloys (DUHEAs). Finally, we created UNb0.5Zr0.5Mo0.5 and UNb0.5Zr0.5Ti0.2Mo0.2 HEAs with outstanding all-round characteristics. Both alloys were composed of a single BCC structure. The hardness and strength of UNb0.5Zr0.5Mo0.5 and UNb0.5Zr0.5Ti0.2Mo0.2 were 305 HB and 1452 MPa, and 297 HB and 1157 MPa, respectively. 
    more » « less
  3. Abstract An oxygen‐resistant refractory high‐entropy alloy is synthesized in microlattice or bulk form by 3D ink‐extrusion printing, interdiffusion, and silicide coating. Additive manufacturing of equiatomic HfNbTaTiZr is implemented by extruding inks containing hydride powders, de‐binding under H2, and sintering under vacuum. The sequential decomposition of hydride powders (HfH2+NbH+TaH0.5+TiH2+ZrH2) is followed by in situ X‐ray diffraction. Upon sintering at 1400 °C for 18 h, a nearly fully densified, equiatomic HfNbTaTiZr alloy is synthesized; on slow cooling, both α‐HCP and β‐BCC phases are formed, but on quenching, a metastable single β‐BCC phase is obtained. Printed and sintered HfNbTaTiZr alloys with ≈1 wt.% O shows excellent mechanical properties at high temperatures. Oxidation resistance is achieved by silicide coating via pack cementation. A small‐size lattice‐core sandwich is fabricated and tested with high‐temperature flames to demonstrate the versatility of this sequential approach (printing, sintering, and siliconizing) for high‐temperature, high‐stress applications of refractory high‐entropy alloys. 
    more » « less
  4. Zinc (Zn) alloys, particularly those incorporating magnesium (Mg), have been explored as potential bioabsorbable metals. However, there is a continued need to enhance the corrosion characteristics of Zn-Mg alloys to fulfill the requirements for biodegradable implants. This work involves a corrosion behavior comparison between severe-plastic-deformation (SPD) processed cast Zn-Mg alloys and their hybrid counterparts, having equivalent nominal compositions. The SPD processing technique used was high-pressure torsion (HPT), and the corrosion behavior was studied as a function of the number of turns (1, 5, 15) for the Zn-3Mg (wt.%) alloy and hybrid and as a function of composition (Mg contents of 3, 10, 30 wt.%) for the hybrid after 15 turns. The results indicated that HPT led to multimodal grain size distributions of ultrafine Mg-rich grains containing MgZn2 and Mg2Zn11 nanoscale intermetallics in a matrix of coarser dislocation-free Zn-rich grains. A greater number of turns resulted in greater corrosion resistance because of the formation of the intermetallic phases. The HPT hybrid was more corrosion resistant than its alloy counterpart because it tended to form the intermetallics more readily than the alloy due to the inhomogeneous conditions of the materials before the HPT processing as well as the non-equilibrium conditions imposed during the HPT processing. The HPT hybrids with greater Mg contents were less corrosion resistant because the addition of Mg led to less noble behavior. 
    more » « less
  5. The yield strength of a CrCoNiSi0.3 medium-entropy alloy is significantly increased from 450 MPa (quasi-static, 0.001 s−1) to 1600 MPa (at a strain rate of 5000 s−1) under dynamic tension, with a considerable ductility of 60%. The high strain-rate sensitivity (SRS) of strength and work hardening is obtained, and the strength SRS reaches 0.408. The dominant deformation mechanisms are abundant multiple-twinning, increasing fractions of deformation twins and phase transformation from face-centered-cubic to hexagonal-close-packed (HCP) phases with a strain rate. A universal dislocation-hardened constitutive model considering the evolution of the twin and HCP transformation is established to predict the flow stress and microstructure evolution. 
    more » « less