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Using sunlight to produce hydrogen gas via photocatalytic water splitting is highly desirable for green energy harvesting and sustainability. In this work, Mn 2+ doped 1-dimensional (1D) CdS nanorods (NRs) with Pt tips ( i.e. , 1D Mn:CdS-Pt NRs) were synthesized for photocatalytic water splitting to generate hydrogen gas. The incorporation of Mn 2+ dopants inside the 1D CdS NRs with a significantly longer lifetime (∼ms) than that of host excitons (∼ns) facilitates charge separation; the electron transfer to metal Pt tips leads to enhanced photocatalytic activity in water splitting redox reactions. The as-synthesized Mn 2+ doped CdS NR-based photocatalyst generated an order of magnitude greater yield of hydrogen gas compared to the undoped CdS NR-based photocatalyst. The enhanced charge transport from the long lifetime excited state of Mn 2+ dopants in light harvesting semiconductor nanomaterials presents a new opportunity to increase the overall photocatalytic performance.
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Photocatalytic Degradation of Azo Dyes in Aqueous Solution Using TiO2 Doped with rGO/CdS under UV Irradiation
Photocatalysis, mainly using TiO2 as a catalyst, has emerged as a promising method to address the issue of wastewater treatment. This study explores the enhanced photocatalytic activity of TiO2 through the introduction of reduced graphene oxide (rGO) and cadmium sulfide (CdS) as selective metal dopants. The incorporation of rGO and CdS into the TiO2 lattice aims to optimize its photocatalytic properties, including bandgap engineering, charge carrier separation, and surface reactivity. The unique combination of CdS and rGO with TiO2 is expected to boost degradation efficiency and reduce the reliance on expensive and potentially harmful sensitizers. This experimental investigation involves the synthesis and characterization of TiO2-based photocatalysts. The photocatalytic degradation of methyl orange (MO) and methylene blue (MB) was assessed under controlled laboratory conditions, studying the influence of metal dopants on degradation kinetics and degradation efficiency. Furthermore, the synthesized photocatalyst is characterized by advanced techniques, including BET, SEM, TEM, XRD, and XPS analyses. The degraded samples were analyzed by UV-Vis spectroscopy. Insights into the photoexcitation and charge transfer processes shed light on the role of metal dopants in enhancing photocatalytic performance. The results demonstrate the potential of a TiO2-rGO-CdS-based photocatalyst in which 100% degradation was achieved within four hours for MO and six hours for MB, confirming efficient azo dye degradation. The findings contribute to understanding the fundamental principles underlying the photocatalytic process and provide valuable guidance for designing and optimizing advanced photocatalytic systems. Ultimately, this research contributes to the development of sustainable and effective technologies for removing azo dyes from various wastewaters, promoting environmental preservation and human well-being.
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- Award ID(s):
- 1914692
- PAR ID:
- 10542013
- Publisher / Repository:
- MDPI
- Date Published:
- Journal Name:
- Processes
- Volume:
- 12
- Issue:
- 7
- ISSN:
- 2227-9717
- Page Range / eLocation ID:
- 1455
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.3390/pr12071455
