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   https://doi.org/10.1021/acsmaterialsau.1c00018  

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2. First-Principles Prediction of Two-Dimensional B 3 C 2 P 3 and B 2 C 4 P 2 : Structural Stability, Fundamental Properties, and Renewable Energy Applications

   https://doi.org/10.1021/acs.jpclett.1c00411  

   Kistanov, Andrey A. ; Shcherbinin, Stepan A. ; Ustiuzhanina, Svetlana V. ; Huttula, Marko ; Cao, Wei ; Nikitenko, Vladimir R. ; Prezhdo, Oleg V. ( April 2021 , The Journal of Physical Chemistry Letters)
3. Antiferromagnetic semiconductor Eu 3 Sn 2 P 4 with Sn–Sn dimer and crown-wrapped Eu

   https://doi.org/10.1039/C9TC03557E  

   Blawat, Joanna ; Swatek, Przemyslaw ; Gui, Xin ; Jin, Rongying ; Xie, Weiwei ( October 2019 , Journal of Materials Chemistry C)

   A novel antiferromagnetic semiconductor, Eu 3 Sn 2 P 4 , has been discovered. Single crystals of Eu 3 Sn 2 P 4 were prepared using the Sn self-flux method. The crystal structure determined by single crystal X-ray diffraction shows that Eu 3 Sn 2 P 4 crystallizes in the orthorhombic structure with the space group Cmca (Pearson Symbol, oP 216). Six Sn–Sn dimers connected by P atoms form a Sn 12 P 24 crown-shaped cluster with a Eu atom located in the center. Magnetization measurements indicate that the system orders antiferromagnetically below a T N ∼14 K at a low field and undergoes a metamagnetic transition at a high field when T < T N . The effective magnetic moment is 7.41(3) μ B per Eu, corresponding to Eu 2+ . The electric resistivity reveals a non-monotonic temperature dependence with non-metallic behavior below ∼60 K, consistent with the band structure calculations. By fitting the data using the thermally activated resistivity formula, we estimate the energy gap to be ∼0.14 eV. Below T N , the resistivity tends to saturate, suggesting the reduction of charge-spin scattering. 

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