This study explores the latent thermal energy storage potential of an organic phase change material with porous copper foam and its applicability in electronic cooling under varying heat load conditions. The organic phase change material, n-eicosane, is known for its inherently low thermal conductivity of 0.15 W/mK, rendering it vulnerable during power spikes despite its abundant latent heat energy for phase transition from solid to liquid. Porous copper foams are often integrated into n-eicosane to enhance the composite’s thermal conductivity. However, the volume fraction of the phase change material in the porous foam that optimally improves the thermal performance can be dependent on the boundary condition, the cut-off temperature, and the thickness. A finite difference numerical model was developed and utilized to ascertain the energy consumption for the composite of n-eicosane with two kinds of porous copper foam with varying porosity under different heat rates, cut-off temperatures, and thickness. In addition, the results are compared with a metallic phase change material (gallium), a material chosen with a similar melting point but significantly high thermal conductivity and volumetric latent heat. For validation of the numerical model and to experimentally verify the effect of boundary condition (heat rate), experimental investigation was performed for n-eicosane and high porosity copper foam composite at varying heat rates to observe its melting and solidification behaviors during continuous operation until a cut-off temperature of 70 ◦C is reached. Experiments reveal that heat rate influences the amount of latent energy storage capability until a cutoff temperature is reached. For broad comparison, the numerical model was used to obtain the accessed energy and power density and generate thermal Ragone plots to compare and characterize pure gallium and n-eicosane - porous foam composite with varying volume fractions, cutoff temperature, and thickness under volumetric and gravimetric constraints. Overall, the proposed framework in the form of thermal Ragone plots effectively delineates the optimal points for various combinations of heat rate, cutoff point, and aspect ratio, affirming its utility for comprehensive design guidelines for PCM-based composites for electronic cooling applications 
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                            Stabilizing an adverse density difference in the presence of phase change
                        
                    
    
            Given two phases in equilibrium in a porous solid, the heavy phase lying above the light phase in a gravitational field, we stabilize this adverse density arrangement by heating from below and derive a formula for how steep the temperature gradient must be to do this. The input temperature gradient has two effects on the stability of our system. Its effect on the heat convection is destabilizing, its effect on the heat conduction at the surface is stabilizing. By directing our attention to the case of zero growth rate, we obtain the critical value of the input temperature gradient as it depends on the permeability of the porous solid, the density difference across the surface, the distance between the planes bounding our system, and the physical properties. Our problem makes connections to the Bénard problem where it has two, one, or no critical points, and to the Rayleigh–Taylor problem where it has no critical points. 
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                            - Award ID(s):
- 2025117
- PAR ID:
- 10547544
- Editor(s):
- -
- Publisher / Repository:
- Springer
- Date Published:
- Journal Name:
- Journal of engineering mathematics
- Edition / Version:
- -
- Volume:
- 147
- Issue:
- 1
- ISSN:
- 0022-0833
- Page Range / eLocation ID:
- 1-23
- Subject(s) / Keyword(s):
- Phase-change Porous media Rayleigh–Taylor stabilization
- Format(s):
- Medium: X Size: 998KB Other: PDF
- Size(s):
- 998KB
- Sponsoring Org:
- National Science Foundation
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