skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Evaluating the Efficiency of Magnetic Treatment for Feed Water in Reverse Osmosis Processes
The paper presents a new methodology for short-term (5–25 min) benchtop tests to evaluate the effectiveness of magnetic treatment of feed water for reducing mineral scaling on a reverse osmosis (RO) membrane. Scale deposition is measured at a controlled level of salt supersaturation in water flowing through an RO unit in once-through mode. A magnetic water conditioner is tested in a transient flow regime when variations of the permeate flux along the flow path are insignificant. Scale formation under these conditions is governed by salt crystallization on the membrane surface. The proposed method was implemented to investigate the influence of magnetic treatment on gypsum deposition on RO membranes in supersaturated aqueous CaSO4/NaCl solutions. The effects of magnetic water treatment on scale formation under our experimental conditions were found to be statistically insignificant with a confidence level of 95%. However, this outcome should not be considered to negate the potential efficiency of magnetic water treatment in specific applications. The proposed methodology of testing under a controlled level of salt supersaturation will also be useful for evaluating the efficiency of other water treatment technologies.  more » « less
Award ID(s):
1822130
PAR ID:
10553338
Author(s) / Creator(s):
; ; ; ; ; ;
Publisher / Repository:
MDPI
Date Published:
Journal Name:
Membranes
Volume:
13
Issue:
7
ISSN:
2077-0375
Page Range / eLocation ID:
641
Subject(s) / Keyword(s):
reverse osmosis mineral scaling testing methodology magnetic treatment scale deposition and morphology
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. null (Ed.)
    Poultry slaughterhouses produce a large amount of wastewater, which is usually treated by conventional methods. The traditional techniques face some challenges, especially the incapability of recovering valuable nutrients and reusing the treated water. Therefore, membrane technology has been widely adopted by researchers due to its enormous advantages over conventional methods. Pressure-driven membranes, such as microfiltration (MF), ultrafiltration (UF), nanofiltration (NF), and reverse osmosis (RO), have been studied to purify poultry slaughterhouse wastewater (PSWW) as a standalone process or an integrated process with other procedures. Membrane technology showed excellent performance by providing high efficiency for pollutant removal and the recovery of water and valuable products. It may remove approximately all the pollutants from PSWW and purify the water to the required level for discharge to the environment and even reuse for industrial poultry processing purposes while being economically efficient. This article comprehensively reviews the treatment and reuse of PSWW with MF, UF, NF, and RO. Most valuable nutrients can be recovered by UF, and high-quality water for reuse in poultry processing can be produced by RO from PSWW. The incredible performance of membrane technology indicates that membrane technology is an alternative approach for treating PSWW. 
    more » « less
  2. To implement sustainable water resource management, the industries that produce a huge amount of wastewater are aiming to recycle wastewater. Reverse osmosis (RO) is an advanced membrane process that can produce potable water from wastewater. However, the presence of diverse pollutants in the wastewater necessitates effective pretreatment to ensure successful RO implementation. This study evaluated the efficiency of microfiltration (MF) and ultrafiltration (UF) as two pretreatment methods prior to RO, i.e., MF-RO and UF-RO, for recycling poultry slaughterhouse wastewater (PSWW). The direct treatment of PSWW with RO (direct RO) was also considered for comparison. In this study, membrane technology serves as a post treatment for PSWW, which was conventionally treated at Sanderson Farm. The results demonstrated that all of the processes, including MF-RO, UF-RO, and direct RO treatment of PSWW, rejected 100% of total phosphorus (TP), over 91.2% of chemical oxygen demand (COD), and 87% of total solids (TSs). Total nitrogen (TN) levels were reduced to 5 mg/L for MF-RO, 4 mg/L for UF-RO, and 9 mg/L for direct RO. In addition, the pretreatment of PSWW with MF and UF increased RO flux from 46.8 L/m2 h to 51 L/m2 h, an increase of approximately 9%. The product water obtained after MF-RO, UF-RO, and direct RO meets the required potable water quality standards for recycling PSWW in the poultry industry. A cost analysis demonstrated that MF-RO was the most economical option among membrane processes, primarily due to MF operating at a lower pressure and having a high water recovery ratio. In contrast, the cost of using RO without MF and UF pretreatments was approximately 2.6 times higher because of cleaning and maintenance expenses related to fouling. This study concluded that MF-RO is a preferable option for recycling PSWW. This pretreatment method would significantly contribute to environmental sustainability by reusing well-treated PSWW for industrial poultry purposes while maintaining cost efficiency. 
    more » « less
  3. To address some challenges of food security and sustainability of the poultry processing industry, a sequential membrane process of ultrafiltration (UF), forward osmosis (FO), and reverse osmosis (RO) is proposed to treat semi-processed poultry slaughterhouse wastewater (PSWW) and water recovery. The pretreatment of PSWW with UF removed 36.7% of chemical oxygen demand (COD), 38.9% of total phosphorous (TP), 24.7% of total solids (TS), 14.5% of total volatile solids (TVS), 27.3% of total fixed solids (TFS), and 12.1% of total nitrogen (TN). Then, the PSWW was treated with FO membrane in FO mode, pressure retarded osmosis (PRO) mode, and L-DOPA coated membrane in the PRO mode. The FO mode was optimal for PSWW treatment by achieving the highest average flux of 10.4 ± 0.2 L/m2-h and the highest pollutant removal efficiency; 100% of COD, 100% of TP, 90.5% of TS, 85.3% of TVS, 92.1% of TFS, and 37.2% of TN. The performance of the FO membrane was entirely restored by flushing the membrane with 0.1% sodium dodecyl sulfate solution. RO significantly removed COD, TS, TVS, TFS, and TP. However, TN was reduced by only 62% because of the high ammonia concentration present in the draw solution. Overall, the sequential membrane process (UF-FO-RO) showed excellent performance by providing high rejection efficiency for pollutant removal and water recovery. 
    more » « less
  4. null (Ed.)
    The decreasing cost of electricity produced using solar and wind and the need to avoid CO 2 emissions from fossil fuels has heightened interest in hydrogen gas production by water electrolysis. Offshore and coastal hydrogen gas production using seawater and renewable electricity is of particular interest, but it is currently economically infeasible due to the high costs of ion exchange membranes and the need to desalinate seawater in existing electrolyzer designs. A new approach is described here that uses relatively inexpensive commercially available membranes developed for reverse osmosis (RO) to selectively transport favorable ions. In an applied electric field, RO membranes have a substantial capacity for proton and hydroxide transport through the active layer while excluding salt anions and cations. A perchlorate salt was used to provide an inert and contained anolyte, with charge balanced by proton and hydroxide ion flow across the RO membrane. Synthetic seawater (NaCl) was used as the catholyte, where it provided continuous hydrogen gas evolution. The RO membrane resistance was 21.7 ± 3.5 Ω cm 2 in 1 M NaCl and the voltages needed to split water in a model electrolysis cell at current densities of 10–40 mA cm −2 were comparable to those found when using two commonly used, more expensive ion exchange membranes. 
    more » « less
  5. Abstract Perfluoroalkyl and polyfluoroalkyl substances (PFASs) are now widely found in aquatic ecosystems, including sources of drinking water and portable water, due to their increasing prevalence. Among different PFAS treatment or separation technologies, nanofiltration (NF) and reverse osmosis (RO) both yield high rejection efficiencies (>95%) of diverse PFAS in water; however, both technologies are affected by many intrinsic and extrinsic factors. This study evaluated the rejection of PFAS of different carbon chain length (e.g., PFOA and PFBA) by two commercial RO and NF membranes under different operational conditions (e.g., applied pressure and initial PFAS concentration) and feed solution matrixes, such as pH (4–10), salinity (0‐ to 1000‐mM NaCl), and organic matters (0–10 mM). We further performed principal component analysis (PCA) to demonstrate the interrelationships of molecular weight (213–499 g·mol−1), membrane characteristics (RO or NF), feed water matrices, and operational conditions on PFAS rejection. Our results confirmed that size exclusion is a primary mechanism of PFAS rejection by RO and NF, as well as the fact that electrostatic interactions are important when PFAS molecules have sizes less than the NF membrane pores. Practitioner PointsTwo commercial RO and NF membranes were both evaluated to remove 10 different PFAS.High transmembrane pressures facilitated permeate recovery and PFAS rejection by RO.Electrostatic repulsion and pore size exclusion are dominant rejection mechanisms for PFAS removal.pH, ionic strength, and organic matters affected PFAS rejection.Mechanisms of PFAS rejection with RO/NF membranes were explained by PCA analysis. 
    more » « less