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This content will become publicly available on July 8, 2025

Title: Zinc Indium Sulfide‐Based Photocatalysts for Selective Organic Transformations
Abstract The burgeoning field of semiconductor‐mediated organic conversion is of paramount significance, with zinc indium sulfide (ZnIn2S4) emerging as a standout candidate owing to its benign nature, optimal bandgap, extensive light absorption spectrum, remarkable physicochemical properties, and straightforward synthesis. This review examines the latest breakthroughs and the trajectory of ZnIn2S4‐based photocatalysts in the realm of selective organic transformation. We start with a distinct overview of the intrinsic physical attributes of ZnIn2S4and the underlying mechanisms driving its efficacy in photocatalytic organic transformations. Subsequently, the preparation methods of ZnIn2S4are summarized. The main focus is the state‐of‐the‐art photocatalytic application of various ZnIn2S4‐based photocatalysts, such as redox reactions, the construction of C−C, C−S and S−S bonds, and the cleavage of C−O, C−C, and C=C bonds. In the conclusion part, we provide our perspectives on the prospective advancements and the remaining challenges that lie ahead in the optimization of ZnIn2S4‐based photocatalysts, with the ultimate goal of enhancing their efficacy for a diverse array of photosynthetic applications. It is anticipated to inspire the strategic engineering of ZnIn2S4and other semiconductor‐based photocatalysts for various artificial photosynthesis reactions.  more » « less
Award ID(s):
1955358
PAR ID:
10558416
Author(s) / Creator(s):
; ; ; ;
Publisher / Repository:
Wiley-VCH GmbH
Date Published:
Journal Name:
ChemCatChem
Volume:
16
Issue:
13
ISSN:
1867-3880
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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