Abstract We present a computational study of sliding between gold clusters and a highly oriented pyrolytic graphite substrate, a material system that exhibits ultra-low friction due to structural lubricity. By means of molecular dynamics, it is found that clusters may undergo spontaneous rotations during manipulation as a result of elastic instability, leading to attenuated friction due to enhanced interfacial incommensurability. In the case of a free cluster, shear stresses exhibit a non-monotonic dependency on the strength of the tip-cluster interaction, whereby rigid clusters experience nearly constant shear stresses. Finally, it is shown that the suppression of the translational degrees of freedom of a cluster’s outermost-layer can partially annihilate out-of-plane phonon vibrations, which leads to a reduction of energy dissipation that is in compliance with Stokesian damping. It is projected that the physical insight attained by the study presented here will result in enhanced control and interpretation of manipulation experiments at structurally lubric contacts.
more »
« less
This content will become publicly available on December 21, 2025
Inhomogeneous Nanoscale Conductivity and Friction on Graphite Terraces Explored via Atomic Force Microscopy
The interplay of conductivity and friction in layered materials such as graphite is an open area of investigation. Here, we measure local conductivity and friction on terraces of freshly cleaved highly oriented pyrolytic graphite via atomic force microscopy under ambient conditions. The graphite surface is found to exhibit a rich electrical landscape, with different terraces exhibiting different levels of conductivity. A peculiar dependency of conductivity on scan direction is observed on some terraces. The terraces that exhibit this dependency are also found to show enhanced friction values. A hypothesis based on tip asymmetry and the puckering effect is proposed to explain the findings. Our results highlight the non-triviality of the electrical and tribological properties of graphite on the nanoscale, as well as their interplay.
more »
« less
- Award ID(s):
- 2131976
- PAR ID:
- 10566848
- Publisher / Repository:
- MDPI
- Date Published:
- Journal Name:
- Lubricants
- Volume:
- 12
- Issue:
- 12
- ISSN:
- 2075-4442
- Page Range / eLocation ID:
- 462
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Bismuth ferrite layers, ∼200-nm-thick, are deposited on SrRuO3-coated DyScO3(110)o substrates in a step-flow growth regime via adsorption-controlled molecular-beam epitaxy. Structural characterization shows the films to be phase pure with substrate-limited mosaicity (0.012° x-ray diffraction ω-rocking curve widths). The film surfaces are atomically smooth (0.2 nm root-mean-square height fluctuations) and consist of 260-nm-wide [11¯1]o-oriented terraces and unit-cell-tall (0.4 nm) step edges. The combination of electrostatic and symmetry boundary conditions promotes two monoclinically distorted BiFeO3 ferroelectric variants, which self-assemble into a pattern with unprecedentedly coherent periodicity, consisting of 145 ± 2-nm-wide stripe domains separated by [001]o-oriented 71° domain walls. The walls exhibit electrical rectification and enhanced conductivity.more » « less
-
ABSTRACT Natural graphite can be exfoliated into thin films by trapping it at the interface between water and heptane [S. J Woltornist, A. J. Oyer, J-M. Y. Carrillo, A.V. Dobrynin, and D.H. Adamson, ACS Nano 7 , 7062 (2013)]. In this work, we add functional elements into these graphitic thin films by introducing additives into the water phase prior to exfoliation. We report the successful incorporation of ZnO nanoparticles thereby enabling the composite films to act as effective ultraviolet photodetectors. In a similar manner, integration of silver nanowires is achieved, which results in an enhancement of the electrical conductivity of graphite.more » « less
-
Abstract Graphite is a commonly used raw material across many industries and the demand for high‐quality graphite has been increasing in recent years, especially as a primary component for lithium‐ion batteries. However, graphite production is currently limited by production shortages, uneven geographical distribution, and significant environmental impacts incurred from conventional processing. Here, an efficient method of synthesizing biomass‐derived graphite from biochar is presented as a sustainable alternative to natural and synthetic graphite. The resulting bio‐graphite equals or exceeds quantitative quality metrics of spheroidized natural graphite, achieving a RamanID/IGratio of 0.051 and crystallite size parallel to the graphene layers (La) of 2.08 µm. This bio‐graphite is directly applied as a raw input to liquid‐phase exfoliation of graphene for the scalable production of conductive inks. The spin‐coated films from the bio‐graphene ink exhibit the highest conductivity among all biomass‐derived graphene or carbon materials, reaching 3.58 ± 0.16 × 104S m−1. Life cycle assessment demonstrates that this bio‐graphite requires less fossil fuel and produces reduced greenhouse gas emissions compared to incumbent methods for natural, synthesized, and other bio‐derived graphitic materials. This work thus offers a sustainable, locally adaptable solution for producing state‐of‐the‐art graphite that is suitable for bio‐graphene and other high‐value products.more » « less
-
Traditional Carbon Fiber Reinforced Plastics (CFRPs), carry high in-plane strength and electrical conductivity but exhibit intrinsic weaknesses in strength, toughness and conductivity in the through-thickness direction (i.e. z-direction). This paper presents a novel approach to align and thread Carbon Nanofibers (CNFs) through the porous medium (Carbon fiber fabric) using an interesting radial-flow alignment method and manufacture a novel CNFs z-threaded CFRP prepreg. This new radial-flow alignment approach is unique and has been found highly effective to z-thread the array of carbon fibers (diameter ~ 7 microns) with numerous long CNFs (length ~ 50-200 microns) under a Scanning Electronic Microscope (SEM) analysis. Experimental tests performed on a cured laminate sample prepared by this novel technique with 1 wt% aligned CNF concentration showed a significant improvement on the z-directional electrical conductivity for direct current (DC). The 1 wt% CNFs z-threaded CFRP was found about 100 times as conductive as the control CFRP; whereas the unaligned 1 wt% CNFs modified CFRP was only about 16 times as conductive as the control sample.more » « less
An official website of the United States government
