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1. Trade-offs between Battery Energy Storage and Hydrogen Storage in Off-Grid Green Hydrogen Systems

   Peng, Jing; Vijayshankar, Sanjana; King, Jennifer; Mathieu, Johanna L (January 2025, Hawaii International Conference on System Sciences (HICSS))

   Green hydrogen, produced using renewables through electrolysis, can be used to reduce emissions in the hard-to-abate industrial sector. Efficient production and large-scale deployment require storage to mitigate electrolyzer degradation and ensure stable hydrogen supply. This paper explores the impacts and trade-offs of battery and hydrogen storage in off-grid wind-to-hydrogen systems, considering degradation of batteries and electrolyzers. Utilizing an optimization model, we examine system performance and costs over a wide range of storage capacities and wind profiles. Our results show that batteries smooth short-term fluctuations and minimize electrolyzer degradation but can experience significant degradation resulting from frequent charge/discharge cycles. Conversely, hydrogen storage provides long-term energy buffering, essential for sustained hydrogen production, but can increase electrolyzer cycling and degradation. Combining battery and hydrogen storage enhances system reliability, reduces component degradation, and reduces operational costs. This highlights the importance of strategic storage investments to improve the performance and costs of green hydrogen systems. 

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2. Enhancing Microgrid Resilience with Green Hydrogen Storage

   https://doi.org/10.1109/PESGM51994.2024.10689148  

   Dhankar, Shreshtha; Chen, Cong; Tong, Lang (July 2024, IEEE)
3. Active disturbance rejection control of metal hydride hydrogen storage

   https://doi.org/10.1016/j.ijhydene.2020.09.169  

   Keow, Alicia Li; Mayhall, Amy; Cescon, Marzia; Chen, Zheng (January 2021, International Journal of Hydrogen Energy)
4. Catalytic hydrogenation enabled by ligand-based storage of hydrogen

   https://doi.org/10.1039/d0cc08236h  

   McNeece, Andrew J.; Jesse, Kate A.; Filatov, Alexander S.; Schneider, Joseph E.; Anderson, John S. (April 2021, Chemical Communications)

   Biology employs exquisite control over proton, electron, H-atom, or H 2 transfer. Similar control in synthetic systems has the potential to facilitate efficient and selective catalysis. Here we report a dihydrazonopyrrole Ni complex where an H 2 equivalent can be stored on the ligand periphery without metal-based redox changes and can be leveraged for catalytic hydrogenations. Kinetic and computational analysis suggests ligand hydrogenation proceeds by H 2 association followed by H–H scission. This complex is an unusual example where a synthetic system can mimic biology's ability to mediate H 2 transfer via secondary coordination sphere-based processes. 

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5. Tuning Crystal Morphology in MOFs for Improved Hydrogen Storage

   https://doi.org/10.1021/acsanm.4c04072  

   Murugavel, Ruthradharshini; Rownaghi, Ali A; Rezaei, Fateme (October 2024, ACS Applied Nano Materials)