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Abstract Thermophotovoltaic (TPV) technology converts heat into electricity using thermal radiation. Increasing operating temperature is a highly effective approach to improving the efficiency of TPV systems. However, most reported TPV selective emitters degrade rapidly via. oxidation as operating temperatures increase. To address this issue, replacing nanostructured oxide‐metal films with oxide–oxide films is a promising way to greatly limit oxidation, even under high‐temperature conditions. This study introduces new all‐oxide photonic crystal designs for high‐temperature stable TPV systems, overcoming limitations of metal phases and offering promising material choices. The designs utilize both yttria‐stabilized zirconia (YSZ)/MgO and CeO2/MgO combinations with a multilayer structure and stable high‐quality growth. Both designsexhibit positive optical dielectric constants with tunable reflectivity, measured via optical characterization. Thermal stability testing using in situ heating X‐ray diffraction (XRD) suggests high‐temperature stability (up to 1000 °C) of both YSZ/MgO and CeO2/MgO systems. The results demonstrate a new and promising approach to improve the high‐temperature stability of TPV systems, which can be extended to a wide range of material selection and potential designs.
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This content will become publicly available on February 4, 2026
Enhanced power density in zero-vacuum-gap thermophotovoltaic devices
Adding an infrared transparent spacer to far-field thermophotovoltaic (TPV) devices boosts power density. This scalable zero-gap design surpasses vacuum blackbody limit and achieves performance comparable to near-field TPV with nanoscale gaps.
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- PAR ID:
- 10574601
- Publisher / Repository:
- Royal Society of Chemistry
- Date Published:
- Journal Name:
- Energy & Environmental Science
- Volume:
- 18
- Issue:
- 3
- ISSN:
- 1754-5692
- Page Range / eLocation ID:
- 1514 to 1523
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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