Abstract Bimetallic Janus nanocrystals have received considerable interest in recent years owing to their unique properties and niche applications. The side‐by‐side distribution of two distinct metals provides a flexible platform for tailoring the optical and catalytic properties of nanocrystals. First, a brief introduction to the structural features of bimetallic Janus nanocrystals, followed by an extensive discussion of the synthetic approaches, is given. The strategies and experimental controls for achieving the Janus structure, as well as the mechanistic understandings, are specifically discussed. Then, a number of intriguing properties and applications enabled by the Janus nanocrystals are highlighted. Finally, this article is concluded with future directions and outlooks with respect to both syntheses and applications of this new class of functional nanomaterials. 
                        more » 
                        « less   
                    This content will become publicly available on January 1, 2026
                            
                            Machine Learning-Assisted X-ray Absorption Analysis of Bimetallic Catalysts
                        
                    
    
            Bimetallic nanoparticles have attracted increasing scientific and technological interest as modules for creating nanoscale materials with unique magnetic, electronic, and chemical properties. The properties of bimetallic NPs are functions of... 
        more » 
        « less   
        
    
    
                            - PAR ID:
- 10594302
- Publisher / Repository:
- Royal Society of Chemistry
- Date Published:
- Journal Name:
- Materials Horizons
- ISSN:
- 2051-6347
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
- 
            
- 
            Balancing strength and ductility is crucial for structural materials, yet often presents a paradoxical challenge. This research focuses on crafting a unique bimetallic structure, combining non-magnetic, stainless steel 316L (SS316L) with limited strength but enhanced ductility and magnetic, martensitic 17-4 PH with higher strength but lower ductility. Utilizing a powder-based laser-directed energy deposition (L-DED) system, two vertical bimetallic configurations (SS316L/17-4 PH) and a radial bimetallic structure (SS316L core encased in 17-4 PH) were fabricated. Monolithic SS316L, 17-4 PH, and a 50% SS316L/50% 17-4 PH mixture were printed. The printed samples' phase, microstructure, room temperature mechanical properties, and fracture morphology were examined in as-printed conditions. Bimetallic samples exhibited both phases, with a smooth grain transition at the interface. Radial bimetallic samples demonstrated higher mechanical strength than other compositions, except 17-4 PH. These findings showcase the potential of the L-DED approach for creating functional components with tailored mechanical properties.more » « less
- 
            Bimetallics are emerging as important materials that often exhibit distinct chemical properties from monometallics. However, there is limited access to homogeneously alloyed bimetallics because of the thermodynamic immiscibility of the constituent elements. Overcoming the inherent immiscibility in bimetallic systems would create a bimetallic library with unique properties. Here, we present a nonequilibrium synthesis strategy to address the immiscibility challenge in bimetallics. As a proof of concept, we synthesize a broad range of homogeneously alloyed Cu-based bimetallic nanoparticles regardless of the thermodynamic immiscibility. The nonequilibrated bimetallic nanoparticles are further investigated as electrocatalysts for carbon monoxide reduction at commercially relevant current densities (>100 mA cm −2 ), in which Cu 0.9 Ni 0.1 shows the highest multicarbon product Faradaic efficiency of ~76% with a current density of ~93 mA cm −2 . The ability to overcome thermodynamic immiscibility in multimetallic synthesis offers freedom to design and synthesize new functional nanomaterials with desired chemical compositions and catalytic properties.more » « less
- 
            null (Ed.)The electrochemical CO 2 reduction reaction (CO 2 RR) to form highly valued chemicals is a sustainable solution to address the environmental issues caused by excessive CO 2 emissions. Generally, it is challenging to achieve high efficiency and selectivity simultaneously in the CO 2 RR due to multi-proton/electron transfer processes and complex reaction intermediates. Among the studied formulations, bimetallic catalysts have attracted significant attention with promising activity, selectivity, and stability. Engineering the atomic arrangement of bimetallic nanocatalysts is a promising strategy for the rational design of structures (intermetallic, core/shell, and phase-separated structures) to improve catalytic performance. This review summarizes the recent advances, challenges, and opportunities in developing bimetallic catalysts for the CO 2 RR. In particular, we firstly introduce the possible reaction pathways on bimetallic catalysts concerning the geometric and electronic properties of intermetallic, core/shell, and phase-separated structures at the atomic level. Then, we critically examine recent advances in crystalline structure engineering for bimetallic catalysts, aiming to establish the correlations between structures and catalytic properties. Finally, we provide a perspective on future research directions, emphasizing current challenges and opportunities.more » « less
- 
            Abstract Bimetallic wire arc additive manufacturing (AM) has traditionally been limited to depositions characterized by single planar interfaces. This study demonstrates a more complex radial interface concept, with in situ mechanical interlocking and as-built properties suggesting a prestressed compressive effect. A 308 L stainless core is surrounded by a mild steel casing, incrementally maintaining the interface throughout the Z-direction. A small difference in the thermal expansion coefficient between these steels creates residual stresses at their interface. X-ray diffraction analysis confirms phase purity and microstructural characterization reveals columnar grain growth independent of layer transitions. Hardness values are consistent with thermal dissipation characteristics, and the compressive strength of the bimetallic structures shows a 33% to 42% improvement over monolithic controls. Our results demonstrate that biomimetic radial bimetallic variation is feasible with improved mechanical response over monolithic compositions, providing a basis for advanced structural design and implementation using arc-based metal AM.more » « less
 An official website of the United States government
An official website of the United States government 
				
			 
					 
					
