Title: High Pressure Synthesis of Rubidium Superhydrides
Through laser-heated diamond anvil cell experiments, we synthesize a series of rubidium superhydrides and explore their properties with synchrotron x-ray powder diffraction and Raman spectroscopy measurements, combined with density functional theory calculations. Upon heating rubidium monohydride embedded in H2 at a pressure of 18 GPa, we form RbH9 −I , which is stable upon decompression down to 8.7 GPa, the lowest stability pressure of any known superhydride. At 22 GPa, another polymorph, RbH9 −II is synthesised at high temperature. Unique to the Rb-H system among binary metal hydrides is that further compression does not promote the formation of polyhydrides with higher hydrogen content. Instead, heating above 87 GPa yields RbH5 , which exhibits two polymorphs ( RbH5 −I and RbH5 −II ). All of the crystal structures comprise a complex network of quasimolecular H2 units and H− anions, with RbH5 providing the first experimental evidence of linear H3− anions. Published by the American Physical Society2025  more » « less
Award ID(s):
2136038
PAR ID:
10600750
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ;
Publisher / Repository:
American Physical Society
Date Published:
Journal Name:
Physical Review Letters
Volume:
134
Issue:
19
ISSN:
0031-9007
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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