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   Wheaton, Jacob; Olson, Madison; Torres, Victor M; Martin, Steve W (January 2023, American Ceramic Society bulletin)

   Glassy solid-state electrolytes present several advantages over other classes of solid-state electrolytes, but some material and design challenges must be overcome prior to commercialization. 

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2. Solid-State NMR Spectroscopy

   https://doi.org/10.1021/ac800573y  

   Dybowski*, Cecil; Bai, Shi (June 2008, Analytical Chemistry)
3. Solid State NMR Spectroscopy

   https://doi.org/10.1021/ac100761m  

   Bai, Shi; Wang, Wei; Dybowski, Cecil (June 2010, Analytical Chemistry)
4. Sulfide‐Based Solid‐State Electrolytes: Synthesis, Stability, and Potential for All‐Solid‐State Batteries

   https://doi.org/10.1002/adma.201901131  

   Zhang, Qing; Cao, Daxian; Ma, Yi; Natan, Avi; Aurora, Peter; Zhu, Hongli (September 2019, Advanced Materials)
5. Physio‐Electrochemically Durable Dry‐Processed Solid‐State Electrolyte Films for All‐Solid‐State Batteries

   https://doi.org/10.1002/adfm.202301341  

   Lee, Dong_Ju; Jang, Jihyun; Lee, Jung‐Pil; Wu, Junlin; Chen, Yu‐Ting; Holoubek, John; Yu, Kunpeng; Ham, So‐Yeon; Jeon, Yuju; Kim, Tae‐Hee; et al (April 2023, Advanced Functional Materials)

   Abstract The dry process is a promising fabrication method for all‐solid‐state batteries (ASSBs) to eliminate energy‐intense drying and solvent recovery steps and to prevent degradation of solid‐state electrolytes (SSEs) in the wet process. While previous studies have utilized the dry process to enable thin SSE films, systematic studies on their fabrication, physical and electrochemical properties, and electrochemical performance are unprecedented. Here, different fabrication parameters are studied to understand polytetrafluoroethylene (PTFE) binder fibrillation and its impact on the physio‐electrochemical properties of SSE films, as well as the cycling stability of ASSBs resulting from such SSEs. A counter‐balancing relation between the physio‐electrochemical properties and cycling stability is observed, which is due to the propagating behavior of PTFE reduction (both chemically and electrochemically) through the fibrillation network, resulting in cell failure from current leakage and ion blockage. By controlling PTFE fibrillation, a bilayer configuration of SSE film to enable physio‐electrochemically durable SSE film for both good cycling stability and charge storage capability of ASSBs is demonstrated. 

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