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1. Stabilizing Ti ₃ C ₂ T _x MXene flakes in air by removing confined water

   https://doi.org/10.1073/pnas.2400084121  

   Fang, Hui; Thakur, Anupma; Zahmatkeshsaredorahi, Amirhossein; Fang, Zhenyao; Rad, Vahid; Shamsabadi, Ahmad A; Pereyra, Claudia; Soroush, Masoud; Rappe, Andrew M; Xu, Xiaoji G; et al (July 2024, Proceedings of the National Academy of Sciences)

   MXenes have demonstrated potential for various applications owing to their tunable surface chemistry and metallic conductivity. However, high temperatures can accelerate MXene film oxidation in air. Understanding the mechanisms of MXene oxidation at elevated temperatures, which is still limited, is critical in improving their thermal stability for high-temperature applications. Here, we demonstrate that Ti ${}_3$C ${}_2$T ${}_x$MXene monoflakes have exceptional thermal stability at temperatures up to 600 ${}^{°}$C in air, while multiflakes readily oxidize in air at 300 ${}^{°}$C. Density functional theory calculations indicate that confined water between Ti ${}_3$C ${}_2$T ${}_x$flakes has higher removal energy than surface water and can thus persist to higher temperatures, leading to oxidation. We demonstrate that the amount of confined water correlates with the degree of oxidation in stacked flakes. Confined water can be fully removed by vacuum annealing Ti ${}_3$C ${}_2$T ${}_x$films at 600 ${}^{°}$C, resulting in substantial stability improvement in multiflake films (can withstand 600 ${}^{°}$C in air). These findings provide fundamental insights into the kinetics of confined water and its role in Ti ${}_3$C ${}_2$T ${}_x$oxidation. This work enables the use of stable monoflake MXenes in high-temperature applications and provides guidelines for proper vacuum annealing of multiflake films to enhance their stability. 

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2. MAPbBr ₃ nanocrystals from aqueous solution for poly(methyl methacrylate)-MAPbBr ₃ nanocrystal films with compression-resistant photoluminescence

   https://doi.org/10.1088/1361-6528/ac59e8  

   Tang, Xiaobing; Zhang, Yulin; Kothalawala, Nadeesha Lakmali; Wen, Xiyu; Kim, Doo Young; Yang, Fuqian (March 2022, Nanotechnology)

   Abstract In this work, we develop an environmental-friendly approach to produce organic-inorganic hybrid MAPbBr 3 (MA = CH 3 NH 3 ) perovskite nanocrystals (PeNCs) and PMMA-MAPbBr 3 NC films with excellent compression-resistant PL characteristics. Deionized water is used as the solvent to synthesize MAPbBr 3 powder instead of conventionally-used hazardous organic solvents. The MAPbBr 3 PeNCs derived from the MAPbBr 3 powder exhibit a high photoluminescence quantum yield (PLQY) of 93.86%. Poly(methyl methacrylate) (PMMA)-MAPbBr 3 NC films made from the MAPbBr 3 PeNCs retain ∼97% and ∼91% of initial PL intensity after 720 h aging in ambient environment at 50 °C and 70 °C, respectively. The PMMA-MAPbBr 3 NC films also exhibit compression-resistant photoluminescent characteristics in contrast to the PMMA-CsPbBr 3 NC films under a compressive stress of 1.6 MPa. The PMMA-MAPbBr 3 NC film integrated with a red emissive film and a blue light emitting source achieves an LCD backlight of ∼114% color gamut of National Television System Committee (NTSC) 1953 standard. 

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3. Thermally generated spin current in the topological insulator Bi ₂ Se ₃

   https://doi.org/10.1126/sciadv.adi4540  

   Jain, Rakshit; Stanley, Max; Bose, Arnab; Richardella, Anthony R.; Zhang, Xiyue S.; Pillsbury, Timothy; Muller, David A.; Samarth, Nitin; Ralph, Daniel C. (December 2023, Science Advances)

   We present measurements of thermally generated transverse spin currents in the topological insulator Bi₂Se₃, thereby completing measurements of interconversions among the full triad of thermal gradients, charge currents, and spin currents. We accomplish this by comparing the spin Nernst magneto-thermopower to the spin Hall magnetoresistance for bilayers of Bi₂Se₃/CoFeB. We find that Bi₂Se₃does generate substantial thermally driven spin currents. A lower bound for the ratio of spin current density to thermal gradient is $\frac{J_s}{{\mathbf{\nabla }}_{\mathit{x}}\mathit{T}}$= (4.9 ± 0.9) × 10⁶ $\left(\frac{\hslash }{2e}\right)\frac{\mathbf{A}{\mathbf{m}}^{-2}}{\mathbf{K}\text{μ}{\mathbf{m}}^{-1}}$, and a lower bound for the magnitude of the spin Nernst ratio is −0.61 ± 0.11. The spin Nernst ratio for Bi₂Se₃is the largest among all materials measured to date, two to three times larger compared to previous measurements for the heavy metals Pt and W. Strong thermally generated spin currents in Bi₂Se₃can be understood via Mott relations to be due to an overall large spin Hall conductivity and its dependence on electron energy. 

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4. High pressure raman spectroscopy and X-ray diffraction of K2Ca(CO3)2 bütschliite: multiple pressure-induced phase transitions in a double carbonate

   https://doi.org/10.1007/s00269-023-01262-5  

   Zeff, G.; Kalkan, B.; Armstrong, K.; Kunz, M.; Williams, Q. (January 2024, Physics and Chemistry of Minerals)

   Abstract The crystal structure and bonding environment of K₂Ca(CO₃)₂bütschliite were probed under isothermal compression via Raman spectroscopy to 95 GPa and single crystal and powder X-ray diffraction to 12 and 68 GPa, respectively. A second order Birch-Murnaghan equation of state fit to the X-ray data yields a bulk modulus,$${K}_{0}=46.9$$ $K_0=46.9$GPa with an imposed value of$${K}_{0}^{\prime}= 4$$ $K_0^{\prime }=4$for the ambient pressure phase. Compression of bütschliite is highly anisotropic, with contraction along thec-axis accounting for most of the volume change. Bütschliite undergoes a phase transition to a monoclinicC2/mstructure at around 6 GPa, mirroring polymorphism within isostructural borates. A fit to the compression data of the monoclinic phase yields$${V}_{0}=322.2$$ $V_0=322.2$ Å³$$,$$ $,$$${K}_{0}=24.8$$ $K_0=24.8$GPa and$${K}_{0}^{\prime}=4.0$$ $K_0^{\prime }=4.0$using a third order fit; the ability to access different compression mechanisms gives rise to a more compressible material than the low-pressure phase. In particular, compression of theC2/mphase involves interlayer displacement and twisting of the [CO₃] units, and an increase in coordination number of the K⁺ion. Three more phase transitions, at ~ 28, 34, and 37 GPa occur based on the Raman spectra and powder diffraction data: these give rise to new [CO₃] bonding environments within the structure. 

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5. Laboratory Study of the Cameron Bands and UV Doublet in the Middle Ultraviolet 180–300 nm by Electron Impact upon CO ₂ with Application to Mars

   https://doi.org/10.3847/1538-4357/ac88c8  

   Lee, Rena A.; Ajello, Joseph M.; Malone, Charles P.; Evans, J. Scott; Veibell, Victoir; Holsclaw, Gregory M.; McClintock, William E.; Hoskins, Alan C.; Jain, Sonal K.; Gérard, Jean-Claude; et al (October 2022, The Astrophysical Journal)

   Abstract We have observed electron impact fluorescence from CO₂to excite the Cameron bands (CBs), CO (a³Π →X¹Σ⁺; 180–280 nm), the first-negative group (1NG) bands, CO⁺(B²Σ⁺→X²Σ⁺; 180–320 nm), the fourth-positive group (4PG) bands, CO (A¹Π →X¹Σ⁺; 111–280 nm), and the UV doublet, CO₂⁺( $\tilde{B}{}^2{\mathrm{\Sigma }}_u^{+}\to \tilde{X}{}^2{\mathrm{\Pi }}_g;$288.3 and 289.6 nm) in the ultraviolet (UV). This wavelength range matches the spectral region of past and present spacecraft equipped to observe UV dayglow and aurora emissions from the thermospheres (100–300 km) of Mars and Venus. Our large vacuum system apparatus is able to measure the emission cross sections of the strongest optically forbidden UV transitions found in planetary spectra. Based on our cross-sectional measurements, previous CB emission cross-sectional errors exceed a factor of 3. The UV doublet lifetime is perturbed through $\tilde{B}{}^2{\mathrm{\Sigma }}_u^{+}-\tilde{A}{}^2{\mathrm{\Pi }}_u$spin–orbit coupling. Forward modeling codes of the Mars dayglow have not been accurate in the mid-UV due to systematic errors in these two emission cross sections. We furnish absolute emission cross sections for several band systems over electron energies 20–100 eV for CO₂. We present a CB lifetime, which together with emission cross sections, furnish a set of fundamental physical constants for electron transport codes such as AURIC (Atmospheric Ultraviolet Radiance Integrated Code). AURIC and Trans-Mars are used in the analysis of UV spectra from the Martian dayglow and aurora. 

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