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Title: Ultrafast Processes in Upper Excited Singlet States of Free and Caged 7-Diethylaminothiocoumarin
The photochemistry and photophysics of thiocarbonyl compounds, analogues of carbonyl compounds with sulfur, have long been overshadowed by their counterparts. However, recent interest in visible light reactions has reignited attention toward these compounds due to their unique excited-state properties. This study delves into the ultrafast dynamics of 7- diethylaminothiocoumarin (TC1), a close analogue of the wellknown probe molecule coumarin 1 (C1), to estimate intersystem crossing rates, understand the mechanisms of fluorescence and phosphorescence, and evaluate TC1’s potential as a solvation dynamics probe. Enclosing TC1 within an organic capsule indicates its potential applications, even in aqueous environments. Ultrafast studies reveal a dominant subpicosecond intersystem crossing process, indicating the importance of upper excited singlet and triplet states in the molecule’s photochemistry. The distinct fluorescence and phosphorescence origins, along with the presence of closely spaced singlet excited states, support the observed efficient intersystem crossing. The sulfur atom alters the excited-state behavior, shedding light on reactive triplet states and paving the way for further investigations.  more » « less
Award ID(s):
2204046
PAR ID:
10626545
Author(s) / Creator(s):
; ; ; ; ;
Publisher / Repository:
American Chemical Society
Date Published:
Journal Name:
The Journal of Physical Chemistry A
Volume:
128
Issue:
33
ISSN:
1089-5639
Page Range / eLocation ID:
6853 to 6863
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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