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1. Disproportionation of Sn(II){CH(SiMe ₃ ) ₂ } ₂ to ·Sn(III){CH(SiMe ₃ ) ₂ } ₃ and ·Sn(I){CH(SiMe ₃ ) ₂ }: Characterization of the Sn(I) Product

   https://doi.org/10.1039/d3cc01542d  

   Mears, Kristian; Nguyen, Gia-Ann; Ruiz, Bronson; Zou, Wenxing; Fettinger, James C; Power, Philip P (May 2023, Chemical Communications)

   Half a century since the photocatalytic disproportionation of Lappert's dialkyl stannylene SnR 2 , R = CH(SiMe 3 ) 2 (1) gave the persistent trivalent radical [·SnR 3 ], the characterization of the corresponding Sn(I) product, ·SnR is now described. It was isolated as the hexastannaprismane Sn 6 R 6 (2), from the reduction of 1 by the Mg(I)-reagent, Mg(BDI Dip ) 2 , (BDI = (DipNCMe) 2 CH, Dip + 2,6-diisopropylphenyl). 

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2. Reactivity of [Ce(NR ₂ ) ₃ ] (R = SiMe ₃ ) with Prospective Carbon Atom Transfer Reagents

   https://doi.org/10.1021/acs.organomet.0c00186  

   Kent, Greggory T.; Staun, Selena L.; Wu, Guang; Hayton, Trevor W. (July 2020, Organometallics)

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3. La[N(SiMe ₃ ) ₂ ] ₃ -Catalyzed Deoxygenative Reduction of Amides with Pinacolborane. Scope and Mechanism

   https://doi.org/10.1021/jacs.0c02446  

   Barger, Christopher J.; Dicken, Rachel D.; Weidner, Victoria L.; Motta, Alessandro; Lohr, Tracy L.; Marks, Tobin J. (April 2020, Journal of the American Chemical Society)

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4. La[N(SiMe ₃ ) ₂ ] ₃ -Catalyzed Ester Reductions with Pinacolborane: Scope and Mechanism of Ester Cleavage

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   Barger, Christopher J.; Motta, Alessandro; Weidner, Victoria L.; Lohr, Tracy L.; Marks, Tobin J. (October 2019, ACS Catalysis)
5. Benzylic Aroylation of Toluenes Mediated by a LiN(SiMe ₃ ) ₂ /Cs ⁺ System

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   Gu, Yuanyun; Zhang, Zhen; Wang, Yan-En; Dai, Ziteng; Yuan, Yaqi; Xiong, Dan; Li, Jie; Walsh, Patrick J.; Mao, Jianyou (January 2022, The Journal of Organic Chemistry)