A promising avenue for the preparation of Gibbs states on a quantum computer is to simulate the physical thermalization process. The Davies generator describes the dynamics of an open quantum system that is in contact with a heat bath. Crucially, it does not require simulation of the heat bath itself, only the system we hope to thermalize. Using the state-of-the-art techniques for quantum simulation of the Lindblad equation, we devise a technique for the preparation of Gibbs states via thermalization as specified by the Davies generator.In doing so, we encounter a severe technical challenge: implementation of the Davies generator demands the ability to estimate the energy of the system unambiguously. That is, each energy of the system must be deterministically mapped to a unique estimate. Previous work showed that this is only possible if the system satisfies an unphysical 'rounding promise' assumption. We solve this problem by engineering a random ensemble of rounding promises that simultaneously solves three problems: First, each rounding promise admits preparation of a 'promised' thermal state via a Davies generator. Second, these Davies generators have a similar mixing time as the ideal Davies generator. Third, the average of these promised thermal states approximates the ideal thermal state.
more »
« less
Control of open quantum systems: The nonequilibrium Green’s function perspective
Manipulations with open quantum systems (such as qubits) are fundamental for any quantum technology. They are the focus of studies involving optimal control theory. Usually, control is achieved through the use of time-dependent external fields when driven system evolution is simulated employing the Davies construction (second-order Markov quantum master equation formulation). As a weak (second order) coupling scheme, the Davies construction is limited in its ability to account for bath-induced coherences. To overcome the limitation, we utilize the nonequilibrium Green’s function method and demonstrate that accounting for the coherences makes a qualitative impact on quantum control studies. We find that accounting for the coherences is especially important when dealing with system evolution involving mixed states.
more »
« less
- Award ID(s):
- 2154323
- PAR ID:
- 10630119
- Publisher / Repository:
- AIP Publishing
- Date Published:
- Journal Name:
- APL Quantum
- Volume:
- 2
- Issue:
- 1
- ISSN:
- 2835-0103
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
What can one infer about the dynamical evolution of quantum systems just by symmetry considerations? For Markovian dynamics in finite dimensions, we present a simple construction that assigns to each symmetry of the generator a family of scalar functions over quantum states that are monotonic under the time evolution. The aforementioned monotones can be utilized to identify states that are non-reachable from an initial state by the time evolution and include all constraints imposed by conserved quantities, providing a generalization of Noether's theorem for this class of dynamics. As a special case, the generator itself can be considered a symmetry, resulting in non-trivial constraints over the time evolution, even if all conserved quantities trivialize. The construction utilizes tools from quantum information-geometry, mainly the theory of monotone Riemannian metrics. We analyze the prototypical cases of dephasing and Davies generators.more » « less
-
Quantum master equations (QMEs) provide a general framework for describing electronic dynamics within a complex molecular system. Off-diagonal QMEs (OD-QMEs) correspond to a family of QMEs that describe the electronic dynamics in the interaction picture based on treating the off-diagonal coupling terms between electronic states as a small perturbation within the framework of second-order perturbation theory. The fact that OD-QMEs are given in terms of the interaction picture makes it non-trivial to obtain Schrödinger picture electronic coherences from them. A key experimental quantity that relies on the ability to obtain accurate Schrödinger picture electronic coherences is the absorption spectrum. In this paper, we propose using a recently introduced procedure for extracting Schrödinger picture electronic coherences from interaction picture inputs to calculate electronic absorption spectra from the electronic dynamics generated by OD-QMEs. The accuracy of the absorption spectra obtained this way is studied in the context of a biexciton benchmark model, by comparing spectra calculated based on time-local and time-nonlocal OD-QMEs to spectra calculated based on a Redfield-type QME and the non-perturbative and quantum-mechanically exact hierarchical equations of motion method.more » « less
-
Quantum coherences, observed as time-dependent beats in ultrafast spectroscopic experiments, arise when light–matter interactions prepare systems in superpositions of states with differing energy and fixed phase across the ensemble. Such coherences have been observed in photosynthetic systems following ultrafast laser excitation, but what these coherences imply about the underlying energy transfer dynamics remains subject to debate. Recent work showed that redox conditions tune vibronic coupling in the Fenna–Matthews–Olson (FMO) pigment–protein complex in green sulfur bacteria, raising the question of whether redox conditions may also affect the long-lived (>100 fs) quantum coherences observed in this complex. In this work, we perform ultrafast two-dimensional electronic spectroscopy measurements on the FMO complex under both oxidizing and reducing conditions. We observe that many excited-state coherences are exclusively present in reducing conditions and are absent or attenuated in oxidizing conditions. Reducing conditions mimic the natural conditions of the complex more closely. Further, the presence of these coherences correlates with the vibronic coupling that produces faster, more efficient energy transfer through the complex under reducing conditions. The growth of coherences across the waiting time and the number of beating frequencies across hundreds of wavenumbers in the power spectra suggest that the beats are excited-state coherences with a mostly vibrational character whose phase relationship is maintained through the energy transfer process. Our results suggest that excitonic energy transfer proceeds through a coherent mechanism in this complex and that the coherences may provide a tool to disentangle coherent relaxation from energy transfer driven by stochastic environmental fluctuations.more » « less
-
We consider the quantum dynamics of a pair of coupled quantum oscillators coupled to a common correlated dissipative environment. The resulting equations of motion for both the operator moments and covariances can be integrated analytically using the Lyapunov equations. We find that for fully correlated and fully anti-correlated environments, the oscillators relax into a phase-synchronized state that persists for long-times when the two oscillators are nearly resonant and (essentially) forever if the two oscillators are in resonance. We identify an exceptional point that indicates the onset of broken symmetry between an unsynchronized and synchronized dynamical phase of the system as correlations within the environment are increased. We also show that the environmental noise correlation leads to quantum entanglement, and all the correlations between the two oscillators are purely quantum mechanical in origin. This work provides a robust mathematical foundation for understanding how long-lived exciton coherences can be linked to vibronic correlation effects.more » « less
An official website of the United States government

