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In the title compound, C8H8ClNO2, the acetamide substituent is twisted out of the phenyl plane, forming a dihedral angle of 58.61 (7)°. In the extended structure, each molecule donates two hydrogen bonds [N—H...O(carbonyl) and O—H...O(carbonyl)] and thus also accepts two such hydrogen bonds. The chlorine atom is not involved in the hydrogen bonding.
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N -(4-Methoxy-2-methyl-5-nitrophenyl)acetamide
In the title compound, C10H12N2O4, the four substituents lie out of the phenyl plane by varying degrees. The methyl C atom lies 0.019 (3) A ˚ out of plane, while the methoxy O and C atoms lie 0.067 (2) and 0.042 (3) A ˚ out of plane, respectively, with the C—C—O—C torsion angle being 3.3 (2). The plane of the nitro group is twisted out of the phenyl plane, forming a dihedral angle of 12.03 (9) with it. The acetamide substituent is twisted considerably more out of the phenyl plane, forming a dihedral angle of 47.24 (6) with it. In the extended structure, the acetamide NH group donates a hydrogen bond to an acetamide carbonyl O atom, thereby forming chains propagating in the [010] direction.
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- Award ID(s):
- 2418415
- PAR ID:
- 10637224
- Publisher / Repository:
- International Union of Crystallography
- Date Published:
- Journal Name:
- IUCrData
- Volume:
- 10
- Issue:
- 6
- ISSN:
- 2414-3146
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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