An official website of the United States government
This content will become publicly available on September 15, 2026
Effect of Ti dopants in Ce 1−x Ti x O 2−δ -supported Ni catalysts: structure, redox properties, and carbon resistance in DRM
- Award ID(s):
- 2154622
- PAR ID:
- 10642675
- Publisher / Repository:
- The Royal Society of Chemistry
- Date Published:
- Journal Name:
- Catalysis Science & Technology
- ISSN:
- 2044-4753
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
Superconductivity and Pronounced Electron‐Phonon Coupling in Rock‐Salt Al 1−x O 1−x and Ti 1−x O 1−xAbstract The highest ambient‐pressure Tc among binary compounds is 40 K (MgB2). Higher Tc is achieved in high‐pressure hydrides or multielement cuprates. Alternatively, are explored superconducting properties of binary, metastable sub‐oxides, that may emerge under extremely low oxygen partial pressure. The emphasis is on the rock‐salt structure, which is known to promote superconductivity, and exploring AlO, ScO, TiO, and NbO. Dynamic lattice stability is achieved by introducing metal and oxygen vacancies in the fashion of Nb1−xO1−x‐type structure (x = ¼). The electron‐phonon (e‐ph) coupling is remarkably large in Al1−xO1−xand Ti1−xO1−x(λ ≈ 2 at x = ¼), with Tc ≈ 35 K according to the Allen–Dynes equation. Significantly, the coupling strength is comparable to that in high‐pressure hydrides, yet, in contrast to hydrides and MgB2, the coupling is largely driven by low frequency phonons. Sc1−xO1−xand Nb1−xO1−xshow significantly smaller λ and Tc. Further, hydrogen intercalation to boost λ and Tc is investigated. Only Ti1−x(O1−xHx) and Nb1−x(O1−xHx) are dynamically stable upon intercalation, where H, respectively, decreases and increases Tc. The effect of H doping on electronic structure and Tc is discussed. Altogether, the study suggests that metal sub‐oxides are promising compounds to achieve strong e‐ph coupling at ambient pressure.more » « less
