skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.

Explore Research Products in the PAR
It may take a few hours for recently added research products to appear in PAR search results.


  • NSF Public Access
  • Search Results
  • Influence of Additives on Flame-Retardant, Thermal, and Mechanical Properties of a Sulfur–Triglyceride Polymer Composite
Title: Influence of Additives on Flame-Retardant, Thermal, and Mechanical Properties of a Sulfur–Triglyceride Polymer Composite
Plastics and composites for consumer goods often require flame retardants (FRs) to mitigate flammability risks. Finding FRs that are effective in new sustainable materials is important for bringing them to the market. This study evaluated various FRs in SunBG90 (a composite made from triglycerides and sulfur)—a high sulfur-content material (HSM) promising for use in Li–S batteries, where flame resistance is critical. SunBG90 was blended with FRs from several classes (inorganic, phosphorus-based, brominated, and nitrogen-containing) to assess compliance with UL94 Burning Test standards. Inorganic FRs showed poor flame retardancy and lower mechanical strength, while organic additives significantly improved fire resistance. The addition of 20 wt. % tetrabromobisphenol A enabled SunBG90 to achieve the highest flame retardancy rating (94V-0), while also enhancing wear resistance (52 IW, ASTM C1353) and bonding strength (26 psi, ASTM C482). Selected organic FRs also enhance compressive strength compared to the FR-free SunBG90. This research highlights the potential of HSMs with traditional FRs to meet stringent fire safety standards while preserving or enhancing the mechanical integrity of HSM composites.  more » « less
Award ID(s):
2203669
PAR ID:
10650094
Author(s) / Creator(s):
; ; ;
Publisher / Repository:
mdpi
Date Published:
Journal Name:
Journal of Composites Science
Volume:
8
Issue:
8
ISSN:
2504-477X
Page Range / eLocation ID:
304
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. ; ; ; (, Scientific Reports)
    Abstract Cultivated natural fibers have a huge possibility for green and sustainable reinforcement for polymers, but their limited load-bearing ability and flammability prevent them from wide applications in composites. According to the beam theory, normal stress is the maximum at the outermost layers but zero at the mid-plane under bending (with (non)linear strain distribution). Shear stress is the maximum at the mid-plane but manageable for most polymers. Accordingly, a laminated composite made of hybrid fiber-reinforced shape memory photopolymer was developed, incorporating strong synthetic glass fibers over a weak core of natural hemp fibers. Even with a significant proportion of natural hemp fibers, the mechanical properties of the hybrid composites were close to those reinforced solely with glass fibers. The composites exhibited good shape memory properties, with at least 52% shape fixity ratio and 71% shape recovery ratio, and 24 MPa recovery stress. After 40 s burning, a hybrid composite still maintained 83.53% of its load carrying capacity. Therefore, in addition to largely maintaining the load carrying capacity through the hybrid reinforcement design, the use of shape memory photopolymer endowed a couple of new functionalities to the composites: the plastically deformed laminated composite beam can largely return to its original shape due to the shape memory effect of the polymer matrix, and the flame retardancy of the polymer matrix makes the flammable hemp fiber survive the fire hazard. The findings of this study present exciting prospects for utilizing low-strength and flammable natural fibers in multifunctional load-bearing composites that possess both flame retardancy and shape memory properties. 
    more » « less
  2. ; ; ; ; (, Chemistry)
    High sulfur-content materials (HSMs) formed via inverse vulcanization of elemental sulfur with animal fats and/or plant oils can exhibit remarkable mechanical strength and chemical resistance, sometimes superior to commercial building products. Adding pozzolan fine materials—fly ash (FA), silica fume (SF), ground granulated blast furnace slag (GGBFS), or metakaolin (MK)—can further improve HSM mechanical properties and stability. Herein, we detail nine materials comprised of rancidified chicken fat, elemental sulfur, and canola or sunflower oil (to yield CFS or GFS, respectively) and, with or without FA, SF, GGBFS, or MK. The base HSMs, CFS90 or GFS90, contained 90 wt% sulfur, 5 wt% chicken fat, and 5 wt% canola or sunflower oil, respectively. For each HSM/fine combination, the resulting material was prepared using a 95:5 mass input ratio of HSM/fine. No material exhibited water uptake >0.2 wt% after immersion in water for 24 h, significantly lower than the 28 wt% observed with ordinary Portland cement (OPC). Impressively, CFS90, GFS90, and all HSM/fine combinations exhibited compressive strength values 15% to 55% greater than OPC. After immersion in 0.5 M H2SO4, CFS90, GFS90, and its derivatives retained 90% to 171% of the initial strength of OPC, whereas OPC disintegrated under these conditions. CFS90, GFS90, and its derivatives collectively show promise as sustainable materials and materials with superior performance versus concrete. 
    more » « less
  3. ; ; ; ; ; ; ; ; ; ; et al (, Angewandte Chemie International Edition)
    Abstract The production of elemental sulfur from petroleum refining has created a technological opportunity to increase the valorization of elemental sulfur by the creation of high‐performance sulfur based plastics with improved thermomechanical properties, elasticity and flame retardancy. We report on a synthetic polymerization methodology to prepare the first example of sulfur based segmented multi‐block polyurethanes (SPUs) and thermoplastic elastomers that incorporate an appreciable amount of sulfur into the final target material. This approach applied both the inverse vulcanization of S8with olefinic alcohols and dynamic covalent polymerizations with dienes to prepare sulfur polyols and terpolyols that were used in polymerizations with aromatic diisocyanates and short chain diols. Using these methods, a new class of high molecular weight, soluble block copolymer polyurethanes were prepared as confirmed by Size Exclusion Chromatography, NMR spectroscopy, thermal analysis, and microscopic imaging. These sulfur‐based polyurethanes were readily solution processed into large area free standing films where both the tensile strength and elasticity of these materials were controlled by variation of the sulfur polyol composition. SPUs with both high tensile strength (13–24 MPa) and ductility (348 % strain at break) were prepared, along with SPU thermoplastic elastomers (578 % strain at break) which are comparable values to classical thermoplastic polyurethanes (TPUs). The incorporation of sulfur into these polyurethanes enhanced flame retardancy in comparison to classical TPUs, which points to the opportunity to impart new properties to polymeric materials as a consequence of using elemental sulfur. 
    more » « less
  4. ; ; ; ; ; (, Materials Advances)
    null (Ed.)
    Renewably-sourced, recyclable materials that can replace or extend the service life of existing technologies are essential to accomplish humanity's quest for sustainable living. In this contribution, remeltable composites were prepared in a highly atom-economical reaction between plant-derived terpenoid alcohols (10 wt% citronellol, geraniol, or farnesol) and elemental sulfur (90 wt%). Investigation into the microstructures led to elucidation of a mechanism for terpenoid polyene cyclization initiated by sulfur-centered radicals. The formation of these cyclic structures contributes significantly to understanding the mechanical properties of the materials and the extent to which linear versus crosslinked network materials are formed. The terpenoid–sulfur composites can be thermally processed at low temperatures of 120 °C without loss of mechanical properties, and the farnesol–sulfur composite so processed exhibits compressive strength 70% higher than required of concrete for residential building. The terpenoid–sulfur composites also resist degradation by oxidizing acid under conditions that disintegrate many commercial composites and cements. In addition to being stronger and more chemically resistant than some commercial products, the terpenoid–sulfur composites can be used to improve the acid resistance of mineral-based Portland cement as well. These terpenoid–sulfur composites thus hold promise as elements of sustainable construction on their own or as additives to extend the operational life of existing technologies, while the cyclization behaviour could be an important contributor in other polymerizations of terpenoids. 
    more » « less
  5. ; ; ; ; (, Journal of Testing and Evaluation)
    Abstract Glass fiber reinforced polymer (GFRP) bars are composite materials that, in the field of civil engineering, serve as an alternative for the internal steel reinforcement of concrete structures. The study and development of these material systems in construction are relatively new, requiring targeted research and development to achieve greater adoption. In this scenario, research and standardization play crucial roles. The development and publication of new test methods, material specifications, and other standards, as well as the improvement of the existing ones, allow for quality control, validation, and acceptance. One of these improvements is the evaluation of precision statements of the different ASTM standards related to the physical-mechanical and durability characterization of GFRP bars used as internal concrete reinforcement. Precision refers to how closely test results obtained under specific conditions agree with each other. A precision statement allows potential users to assess the test method’s general suitability for their intended applications. It should provide guidance on the type of variation that can be expected between test results when the method is used in one or more competent laboratories. The present study aims to enhance the precision statements in ASTM standards pertaining to the geometric, material, mechanical, and physical properties required for GFRP bars in concrete reinforcement, including ASTM standards like ASTM D7205M-21, Standard Test Method for Tensile Properties of Fiber Reinforced Polymer Matrix Composite Bars; ASTM D7617M-11(2017), Standard Test Method for Transverse Shear Strength of Fiber-Reinforced Polymer Matrix Composite Bars; and ASTM D7913M-14(2020), Standard Test Method for Bond Strength of Fiber-Reinforced Polymer Matrix Composite Bars to Concrete by Pullout Testing, while in accordance with the statistical procedures and calculation methods outlined in ASTM Practices ASTM E177-20, Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods, and ASTM E691-22, Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method. 
    more » « less
  • Citation Formats
  • MLA
  • APA
  • Chicago
  • BibTeX
  • Save / Share this Record
  • Send to Email