More Like this

1. Photoassisted Radical Depolymerization

   https://doi.org/10.1021/acsmacrolett.2c00603  

   Young, James B.; Bowman, Jared I.; Eades, Cabell B.; Wong, Alexander J.; Sumerlin, Brent S. (December 2022, ACS Macro Letters)
2. Isomer-driven polymerization, depolymerization, and reconstruction

   https://doi.org/10.1039/D4PY01281J  

   Wakefield_IV, Herbert; Fromel, Nicholas J; Jiang, Jennifer; Kevlishvili, Ilia; Yao, Yunxin; Craig, Stephen L; Kulik, Heather J; Klausen, Rebekka S (December 2024, Polymer Chemistry)

   We report that differences in ring strain enthalpy betweencisandtransisomers of sila-cycloheptene provide a driving force for both polymerization and depolymerizationviaolefin metathesis. 

   more » « less
3. Thermodynamics of silica depolymerization with alcohols

   https://doi.org/10.1016/j.poly.2020.114562  

   Torgunrud, Jordan L.; Faria, Alejandro J.; Miller, Stephen A. (September 2020, Polyhedron)
4. Depolymerization of Polymethacrylates by Iron ATRP

   https://doi.org/10.1021/acs.macromol.2c01712  

   Martinez, Michael R.; Schild, Dirk; De Luca Bossa, Ferdinando; Matyjaszewski, Krzysztof (December 2022, Macromolecules)
5. Depolymerization of polystyrene under ambient conditions

   https://doi.org/10.1039/d0nj05984f  

   Balema, Viktor P.; Hlova, Ihor Z.; Carnahan, Scott L.; Seyedi, Mastooreh; Dolotko, Oleksandr; Rossini, Aaron J.; Luzinov, Igor (February 2021, New Journal of Chemistry)

   null (Ed.)

   Depolymerization of the addition polymer polystyrene to monomeric styrene is facilitated by mechanochemical processing at room temperature under ambient atmosphere. The reaction occurs in metal-based milling media in concert with scission of macromolecular chains that generates carbon-centered free-radicals detectable by EPR spectroscopy, even though the processing is performed in air. 

   more » « less