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Title: The Divergent Reduction Chemistry of Ln(II) Bis(terphenylthiolate) Complexes, Ln(SAr iPr6 ) 2 , Leads to KLn(μ-SAr iPr6 ) 2 , C─H Bond Activation Products, and Two-Electron Reduction Reactivity
Award ID(s):
2452677 2503294
PAR ID:
10677812
Author(s) / Creator(s):
; ; ; ; ;
Publisher / Repository:
American Chemical Society
Date Published:
Journal Name:
Journal of the American Chemical Society
Volume:
147
Issue:
38
ISSN:
0002-7863
Page Range / eLocation ID:
34249 to 34255
Subject(s) / Keyword(s):
rare-earth metal, terphenylthiolate, C-H bond activation, two electron reduction
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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  1. Attractive London dispersion effects were found to be responsible forca.half of the dissociation energy of the thiolate ligands in the first examples of M(EAriPr6)3complexes of any metal with any donor [AriPr6= C6H3-2,6-(C6H2-2,4,6-iPr3)2]. 
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